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(2-{ 1,1-Bis(hydroxymethyl)-2-oxidoethyl iminomethyl}-4-chlorophenolato- kappa O-3,N,O ')dibutyltin(IV)

In the title compound, [Sn(C4H9)2(C11H12BrNO4)], the Schiff base ligand chelates to the SnIV atom through the two deprotonated hydroxy groups, as well as through the N atom, to confer an overall cis-C2SnNO2 trigonal-bipyramidal geometry at the SnIV atom [C-Sn-C = 129.92 (9)°]. The remaining methylen...

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Main Authors: Lee, S.M., Lo, K.M., Ali, Hapipah Mohd
Format: Article
Language:English
Published: International Union of Crystallography 2010
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/5297/1/Lee-2010-%282-%7B_1%2C1-Bis%28hydroxy.pdf
http://eprints.um.edu.my/5297/
http://scripts.iucr.org/cgi-bin/paper?S1600536810021872
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spelling my.um.eprints.52972019-01-29T09:16:51Z http://eprints.um.edu.my/5297/ (2-{ 1,1-Bis(hydroxymethyl)-2-oxidoethyl iminomethyl}-4-chlorophenolato- kappa O-3,N,O ')dibutyltin(IV) Lee, S.M. Lo, K.M. Ali, Hapipah Mohd QD Chemistry In the title compound, [Sn(C4H9)2(C11H12BrNO4)], the Schiff base ligand chelates to the SnIV atom through the two deprotonated hydroxy groups, as well as through the N atom, to confer an overall cis-C2SnNO2 trigonal-bipyramidal geometry at the SnIV atom [C-Sn-C = 129.92 (9)°]. The remaining methylenehydroxy groups engage in O-H...O hydrogen bonding with the O atoms of adjacent molecules, leading to infinite supramolecular chains propagating in [001]. International Union of Crystallography 2010 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5297/1/Lee-2010-%282-%7B_1%2C1-Bis%28hydroxy.pdf Lee, S.M. and Lo, K.M. and Ali, Hapipah Mohd (2010) (2-{ 1,1-Bis(hydroxymethyl)-2-oxidoethyl iminomethyl}-4-chlorophenolato- kappa O-3,N,O ')dibutyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66. M793-U719. ISSN 1600-5368 http://scripts.iucr.org/cgi-bin/paper?S1600536810021872 10.1107/s1600536810021872
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
language English
topic QD Chemistry
spellingShingle QD Chemistry
Lee, S.M.
Lo, K.M.
Ali, Hapipah Mohd
(2-{ 1,1-Bis(hydroxymethyl)-2-oxidoethyl iminomethyl}-4-chlorophenolato- kappa O-3,N,O ')dibutyltin(IV)
description In the title compound, [Sn(C4H9)2(C11H12BrNO4)], the Schiff base ligand chelates to the SnIV atom through the two deprotonated hydroxy groups, as well as through the N atom, to confer an overall cis-C2SnNO2 trigonal-bipyramidal geometry at the SnIV atom [C-Sn-C = 129.92 (9)°]. The remaining methylenehydroxy groups engage in O-H...O hydrogen bonding with the O atoms of adjacent molecules, leading to infinite supramolecular chains propagating in [001].
format Article
author Lee, S.M.
Lo, K.M.
Ali, Hapipah Mohd
author_facet Lee, S.M.
Lo, K.M.
Ali, Hapipah Mohd
author_sort Lee, S.M.
title (2-{ 1,1-Bis(hydroxymethyl)-2-oxidoethyl iminomethyl}-4-chlorophenolato- kappa O-3,N,O ')dibutyltin(IV)
title_short (2-{ 1,1-Bis(hydroxymethyl)-2-oxidoethyl iminomethyl}-4-chlorophenolato- kappa O-3,N,O ')dibutyltin(IV)
title_full (2-{ 1,1-Bis(hydroxymethyl)-2-oxidoethyl iminomethyl}-4-chlorophenolato- kappa O-3,N,O ')dibutyltin(IV)
title_fullStr (2-{ 1,1-Bis(hydroxymethyl)-2-oxidoethyl iminomethyl}-4-chlorophenolato- kappa O-3,N,O ')dibutyltin(IV)
title_full_unstemmed (2-{ 1,1-Bis(hydroxymethyl)-2-oxidoethyl iminomethyl}-4-chlorophenolato- kappa O-3,N,O ')dibutyltin(IV)
title_sort (2-{ 1,1-bis(hydroxymethyl)-2-oxidoethyl iminomethyl}-4-chlorophenolato- kappa o-3,n,o ')dibutyltin(iv)
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/5297/1/Lee-2010-%282-%7B_1%2C1-Bis%28hydroxy.pdf
http://eprints.um.edu.my/5297/
http://scripts.iucr.org/cgi-bin/paper?S1600536810021872
_version_ 1643687537645977600
score 13.211869

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