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N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dicyclohexyltin(IV)

The environment at the Sn-IV atom in the title compound, [Sn(C6H11)(2)(C18H11BrN2O3)], is distorted trigonal-bipyramidal, with the two cyclohexyl groups and the imino N atom forming the equatorial plane. The axial O-Sn-O angle is 155.97 (9)degrees. The presence of an intramolecular O-H center dot ce...

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Bibliographic Details
Main Authors: Lee, S.M., Lo, K.M., Ali, Hapipah Mohd
Format: Article
Language:English
Published: International Union of Crystallography 2010
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/5280/1/Lee-2010-N_%27-%285-Bromo-2-oxido.pdf
http://eprints.um.edu.my/5280/
http://scripts.iucr.org/cgi-bin/paper?S1600536810001145
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spelling my.um.eprints.52802019-01-29T08:56:38Z http://eprints.um.edu.my/5280/ N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dicyclohexyltin(IV) Lee, S.M. Lo, K.M. Ali, Hapipah Mohd QD Chemistry The environment at the Sn-IV atom in the title compound, [Sn(C6H11)(2)(C18H11BrN2O3)], is distorted trigonal-bipyramidal, with the two cyclohexyl groups and the imino N atom forming the equatorial plane. The axial O-Sn-O angle is 155.97 (9)degrees. The presence of an intramolecular O-H center dot center dot center dot N hydrogen bond in the Schiff base ligand helps to stabilize the overall structure. International Union of Crystallography 2010 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5280/1/Lee-2010-N_%27-%285-Bromo-2-oxido.pdf Lee, S.M. and Lo, K.M. and Ali, Hapipah Mohd (2010) N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dicyclohexyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66. M162-U717. ISSN 1600-5368 http://scripts.iucr.org/cgi-bin/paper?S1600536810001145 10.1107/s1600536810001145
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
language English
topic QD Chemistry
spellingShingle QD Chemistry
Lee, S.M.
Lo, K.M.
Ali, Hapipah Mohd
N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dicyclohexyltin(IV)
description The environment at the Sn-IV atom in the title compound, [Sn(C6H11)(2)(C18H11BrN2O3)], is distorted trigonal-bipyramidal, with the two cyclohexyl groups and the imino N atom forming the equatorial plane. The axial O-Sn-O angle is 155.97 (9)degrees. The presence of an intramolecular O-H center dot center dot center dot N hydrogen bond in the Schiff base ligand helps to stabilize the overall structure.
format Article
author Lee, S.M.
Lo, K.M.
Ali, Hapipah Mohd
author_facet Lee, S.M.
Lo, K.M.
Ali, Hapipah Mohd
author_sort Lee, S.M.
title N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dicyclohexyltin(IV)
title_short N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dicyclohexyltin(IV)
title_full N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dicyclohexyltin(IV)
title_fullStr N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dicyclohexyltin(IV)
title_full_unstemmed N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dicyclohexyltin(IV)
title_sort n '-(5-bromo-2-oxidobenzylidene-kappa o)-3-hydroxy-2-naphthohydrazidato-kappa n-2 ',o dicyclohexyltin(iv)
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/5280/1/Lee-2010-N_%27-%285-Bromo-2-oxido.pdf
http://eprints.um.edu.my/5280/
http://scripts.iucr.org/cgi-bin/paper?S1600536810001145
_version_ 1643687533297532928
score 13.187197

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