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Dichlorido{N,N-dimethyl-N '- 1-(2pyridyl) ethylidene ethane-1,2-diamine-k(3) N,N ',N ''}zinc

The asymmetric unit of the title compound, [ZnCl2(C11H17N3)], contains two independent pentacoordinate Zn-II complex molecules. In each molecule, the metal atom is coordinated by an N,N ',N ''-tridenate Schiff base and two Cl atoms in a distorted square-pyramidal geometry. The two mol...

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Main Authors: Gwaram, N.S., Ali, Hapipah Mohd, Khaledi, H.
格式: Article
語言:English
出版: International Union of Crystallography 2011
主題:
QD Chemistry
在線閱讀:http://eprints.um.edu.my/5254/1/Gwaram-2011-Dichlorido%7BN%2CN-dimet.pdf
http://eprints.um.edu.my/5254/
http://journals.iucr.org/e/issues/2011/08/00/om2444/om2444.pdf
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spelling my.um.eprints.52542019-01-30T00:58:54Z http://eprints.um.edu.my/5254/ Dichlorido{N,N-dimethyl-N '- 1-(2pyridyl) ethylidene ethane-1,2-diamine-k(3) N,N ',N ''}zinc Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. QD Chemistry The asymmetric unit of the title compound, [ZnCl2(C11H17N3)], contains two independent pentacoordinate Zn-II complex molecules. In each molecule, the metal atom is coordinated by an N,N ',N ''-tridenate Schiff base and two Cl atoms in a distorted square-pyramidal geometry. The two molecules differ little in their geometry, but more in their intermolecular interactions. In the crystal, adjacent molecules are connected via C-H center dot center dot center dot Cl interactions into a three-dimensional supramolecular structure. The network is supplemented by pi-pi interactions formed between the aromatic rings of pairs of the symmetry-related molecules [centroid-centroid distances = 3.6255 (10) and 3.7073 (10) angstrom]. The crystal lattice contains void spaces with a size of 52 angstrom(3). International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5254/1/Gwaram-2011-Dichlorido%7BN%2CN-dimet.pdf Gwaram, N.S. and Ali, Hapipah Mohd and Khaledi, H. (2011) Dichlorido{N,N-dimethyl-N '- 1-(2pyridyl) ethylidene ethane-1,2-diamine-k(3) N,N ',N ''}zinc. Acta Crystallographica Section E: Structure Reports Online, 67. M1027-U291. ISSN 1600-5368 http://journals.iucr.org/e/issues/2011/08/00/om2444/om2444.pdf 10.1107/s1600536811025669
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
language English
topic QD Chemistry
spellingShingle QD Chemistry
Gwaram, N.S.
Ali, Hapipah Mohd
Khaledi, H.
Dichlorido{N,N-dimethyl-N '- 1-(2pyridyl) ethylidene ethane-1,2-diamine-k(3) N,N ',N ''}zinc
description The asymmetric unit of the title compound, [ZnCl2(C11H17N3)], contains two independent pentacoordinate Zn-II complex molecules. In each molecule, the metal atom is coordinated by an N,N ',N ''-tridenate Schiff base and two Cl atoms in a distorted square-pyramidal geometry. The two molecules differ little in their geometry, but more in their intermolecular interactions. In the crystal, adjacent molecules are connected via C-H center dot center dot center dot Cl interactions into a three-dimensional supramolecular structure. The network is supplemented by pi-pi interactions formed between the aromatic rings of pairs of the symmetry-related molecules [centroid-centroid distances = 3.6255 (10) and 3.7073 (10) angstrom]. The crystal lattice contains void spaces with a size of 52 angstrom(3).
format Article
author Gwaram, N.S.
Ali, Hapipah Mohd
Khaledi, H.
author_facet Gwaram, N.S.
Ali, Hapipah Mohd
Khaledi, H.
author_sort Gwaram, N.S.
title Dichlorido{N,N-dimethyl-N '- 1-(2pyridyl) ethylidene ethane-1,2-diamine-k(3) N,N ',N ''}zinc
title_short Dichlorido{N,N-dimethyl-N '- 1-(2pyridyl) ethylidene ethane-1,2-diamine-k(3) N,N ',N ''}zinc
title_full Dichlorido{N,N-dimethyl-N '- 1-(2pyridyl) ethylidene ethane-1,2-diamine-k(3) N,N ',N ''}zinc
title_fullStr Dichlorido{N,N-dimethyl-N '- 1-(2pyridyl) ethylidene ethane-1,2-diamine-k(3) N,N ',N ''}zinc
title_full_unstemmed Dichlorido{N,N-dimethyl-N '- 1-(2pyridyl) ethylidene ethane-1,2-diamine-k(3) N,N ',N ''}zinc
title_sort dichlorido{n,n-dimethyl-n '- 1-(2pyridyl) ethylidene ethane-1,2-diamine-k(3) n,n ',n ''}zinc
publisher International Union of Crystallography
publishDate 2011
url http://eprints.um.edu.my/5254/1/Gwaram-2011-Dichlorido%7BN%2CN-dimet.pdf
http://eprints.um.edu.my/5254/
http://journals.iucr.org/e/issues/2011/08/00/om2444/om2444.pdf
_version_ 1643687527192723456
score 13.154949

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