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Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}manganese(II)

In the title compound, [MnCl2(C13H19N3O)], the Mn-II ion is pentacoordinated in a distorted square-pyramidal geometry. The coordination environment is defined by the N,N',N ''-tridentate Schiff base ligand and one Cl atom in the basal positions and one Cl atom in the apical position....

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Main Authors: Hisham, N.A.I., Ali, Hapipah Mohd, Khaledi, H., Gwaram, N.S.
Format: Article
Language:English
Published: International Union of Crystallography 2011
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/5235/1/Hisham-2011-Dichlorido%7B2-morphol.pdf
http://eprints.um.edu.my/5235/
http://scripts.iucr.org/cgi-bin/paper?S1600536810050221
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spelling my.um.eprints.52352019-01-30T00:57:21Z http://eprints.um.edu.my/5235/ Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}manganese(II) Hisham, N.A.I. Ali, Hapipah Mohd Khaledi, H. Gwaram, N.S. QD Chemistry In the title compound, [MnCl2(C13H19N3O)], the Mn-II ion is pentacoordinated in a distorted square-pyramidal geometry. The coordination environment is defined by the N,N',N ''-tridentate Schiff base ligand and one Cl atom in the basal positions and one Cl atom in the apical position. In the crystal, intermolecular C-H center dot center dot center dot Cl hydrogen bonds link the molecules into a three-dimensional network. An intramolecular C-H center dot center dot center dot Cl hydrogen bond is also observed. International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5235/1/Hisham-2011-Dichlorido%7B2-morphol.pdf Hisham, N.A.I. and Ali, Hapipah Mohd and Khaledi, H. and Gwaram, N.S. (2011) Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}manganese(II). Acta Crystallographica Section E: Structure Reports Online, 67. M41-U515. ISSN 1600-5368 http://scripts.iucr.org/cgi-bin/paper?S1600536810050221 10.1107/s1600536810050221
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
language English
topic QD Chemistry
spellingShingle QD Chemistry
Hisham, N.A.I.
Ali, Hapipah Mohd
Khaledi, H.
Gwaram, N.S.
Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}manganese(II)
description In the title compound, [MnCl2(C13H19N3O)], the Mn-II ion is pentacoordinated in a distorted square-pyramidal geometry. The coordination environment is defined by the N,N',N ''-tridentate Schiff base ligand and one Cl atom in the basal positions and one Cl atom in the apical position. In the crystal, intermolecular C-H center dot center dot center dot Cl hydrogen bonds link the molecules into a three-dimensional network. An intramolecular C-H center dot center dot center dot Cl hydrogen bond is also observed.
format Article
author Hisham, N.A.I.
Ali, Hapipah Mohd
Khaledi, H.
Gwaram, N.S.
author_facet Hisham, N.A.I.
Ali, Hapipah Mohd
Khaledi, H.
Gwaram, N.S.
author_sort Hisham, N.A.I.
title Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}manganese(II)
title_short Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}manganese(II)
title_full Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}manganese(II)
title_fullStr Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}manganese(II)
title_full_unstemmed Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}manganese(II)
title_sort dichlorido{2-morpholino-n- 1-(2-pyridyl)ethylidene ethanamine-kappa n-3,n ',n ''}manganese(ii)
publisher International Union of Crystallography
publishDate 2011
url http://eprints.um.edu.my/5235/1/Hisham-2011-Dichlorido%7B2-morphol.pdf
http://eprints.um.edu.my/5235/
http://scripts.iucr.org/cgi-bin/paper?S1600536810050221
_version_ 1643687521636319232
score 13.211869

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