3-(3-Chloro-2-hydroxyphenyl)-1-phenyl-1H-pyrazole-4-carbaldehyde
In the title compound, C16H11ClN2O2, the pyrazole ring makes dihedral angles of 11.88 (13) and 22.33 (13)degrees with the 3-chloro-2-hydroxybenzene group and phenyl rings, respectively. The phenolic hydroxy group forms an intramolecular O-H center dot center dot center dot N hydrogen bond with the i...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5213/1/Lokhande-2011-3-%283-Chloro-2-hydrox.pdf http://eprints.um.edu.my/5213/ http://scripts.iucr.org/cgi-bin/paper?S1600536811038025 |
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| Summary: | In the title compound, C16H11ClN2O2, the pyrazole ring makes dihedral angles of 11.88 (13) and 22.33 (13)degrees with the 3-chloro-2-hydroxybenzene group and phenyl rings, respectively. The phenolic hydroxy group forms an intramolecular O-H center dot center dot center dot N hydrogen bond with the imine N atom of the pyrazole unit. The formyl group is virtually coplanar with the pyrazole ring [dihedral angle = 4.5 (19)degrees] and acts as an acceptor in an intramolecular C-H center dot center dot center dot O hydrogen bond closing seven-membered ring. In the crystal, adjacent molecules are linked through C-H center dot center dot center dot O hydrogen bonds into infinite chains along the b axis. |
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