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Di-mu-thiocyanato-kappa N-2:S;kappa S-2:N-bis({2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}(thiocyanato-kappa N)cadmium)

In the title complex, [Cd-2(NCS)(4)(C13H19N3O)(2)], the two Cd-II ions are bridged by a pair of thiocyanate N:S-bridging ligands around an inversion center. One terminal thiocyanate N atom and one N,N',N ''-tridentate Schiff base ligand complete a distorted CdN5S octahedral geometry a...

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Main Authors: Gwaram, N.S., Ali, Hapipah Mohd, Khaledi, H., Hisham, N.A.I.
Format: Article
Language:English
Published: International Union of Crystallography 2011
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/5210/1/Gwaram-2011-Di-mu-thiocyanato-ka.pdf
http://eprints.um.edu.my/5210/
http://scripts.iucr.org/cgi-bin/paper?S1600536811002480
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spelling my.um.eprints.52102019-01-30T00:54:36Z http://eprints.um.edu.my/5210/ Di-mu-thiocyanato-kappa N-2:S;kappa S-2:N-bis({2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}(thiocyanato-kappa N)cadmium) Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. Hisham, N.A.I. QD Chemistry In the title complex, [Cd-2(NCS)(4)(C13H19N3O)(2)], the two Cd-II ions are bridged by a pair of thiocyanate N:S-bridging ligands around an inversion center. One terminal thiocyanate N atom and one N,N',N ''-tridentate Schiff base ligand complete a distorted CdN5S octahedral geometry about each Cd-II atom. In the crystal, the Schiff base aromatic rings of adjacent molecules are arranged above each other into infinite chains along the a axis with alternate centroid-centroid separations of 3.5299 (13) and 3.7857 (13) angstrom. International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5210/1/Gwaram-2011-Di-mu-thiocyanato-ka.pdf Gwaram, N.S. and Ali, Hapipah Mohd and Khaledi, H. and Hisham, N.A.I. (2011) Di-mu-thiocyanato-kappa N-2:S;kappa S-2:N-bis({2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}(thiocyanato-kappa N)cadmium). Acta Crystallographica Section E: Structure Reports Online, 67. M251-U1438. ISSN 1600-5368 http://scripts.iucr.org/cgi-bin/paper?S1600536811002480 10.1107/s1600536811002480
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
language English
topic QD Chemistry
spellingShingle QD Chemistry
Gwaram, N.S.
Ali, Hapipah Mohd
Khaledi, H.
Hisham, N.A.I.
Di-mu-thiocyanato-kappa N-2:S;kappa S-2:N-bis({2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}(thiocyanato-kappa N)cadmium)
description In the title complex, [Cd-2(NCS)(4)(C13H19N3O)(2)], the two Cd-II ions are bridged by a pair of thiocyanate N:S-bridging ligands around an inversion center. One terminal thiocyanate N atom and one N,N',N ''-tridentate Schiff base ligand complete a distorted CdN5S octahedral geometry about each Cd-II atom. In the crystal, the Schiff base aromatic rings of adjacent molecules are arranged above each other into infinite chains along the a axis with alternate centroid-centroid separations of 3.5299 (13) and 3.7857 (13) angstrom.
format Article
author Gwaram, N.S.
Ali, Hapipah Mohd
Khaledi, H.
Hisham, N.A.I.
author_facet Gwaram, N.S.
Ali, Hapipah Mohd
Khaledi, H.
Hisham, N.A.I.
author_sort Gwaram, N.S.
title Di-mu-thiocyanato-kappa N-2:S;kappa S-2:N-bis({2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}(thiocyanato-kappa N)cadmium)
title_short Di-mu-thiocyanato-kappa N-2:S;kappa S-2:N-bis({2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}(thiocyanato-kappa N)cadmium)
title_full Di-mu-thiocyanato-kappa N-2:S;kappa S-2:N-bis({2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}(thiocyanato-kappa N)cadmium)
title_fullStr Di-mu-thiocyanato-kappa N-2:S;kappa S-2:N-bis({2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}(thiocyanato-kappa N)cadmium)
title_full_unstemmed Di-mu-thiocyanato-kappa N-2:S;kappa S-2:N-bis({2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}(thiocyanato-kappa N)cadmium)
title_sort di-mu-thiocyanato-kappa n-2:s;kappa s-2:n-bis({2-morpholino-n- 1-(2-pyridyl)ethylidene ethanamine-kappa n-3,n ',n ''}(thiocyanato-kappa n)cadmium)
publisher International Union of Crystallography
publishDate 2011
url http://eprints.um.edu.my/5210/1/Gwaram-2011-Di-mu-thiocyanato-ka.pdf
http://eprints.um.edu.my/5210/
http://scripts.iucr.org/cgi-bin/paper?S1600536811002480
_version_ 1643687515177091072
score 13.19449

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