2-{ 2-(Piperazin-4-ium-1-yl)ethyliminio methyl}phenolate 0.06-chloride 0.94-perchlorate
The structure of the title salt, C13H20N3O+center dot 0.94ClO(4)(-)center dot 0.06Cl(-), contains a zwitterionic Schiff base with a net positive charge and a perchlorate anion having substitutional disorder with Cl. In the cation, the azomethine N atom is protonated and donates hydrogen bonds to the...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011
|
| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5206/1/Reisi-2011-2-%7B_2-%28Piperazin-4-i.pdf http://eprints.um.edu.my/5206/ http://scripts.iucr.org/cgi-bin/paper?S1600536811042255 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Summary: | The structure of the title salt, C13H20N3O+center dot 0.94ClO(4)(-)center dot 0.06Cl(-), contains a zwitterionic Schiff base with a net positive charge and a perchlorate anion having substitutional disorder with Cl. In the cation, the azomethine N atom is protonated and donates hydrogen bonds to the phenolate O atom and to the tertiary N atom of the piperazine ring. In the crystal, two Schiff base molecules are linked about a center of inversion by a pair of N-H center dot center dot center dot O hydrogen bonds. The resulting dimers are N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonded to the perchlorate anions, forming a three-dimensional structure. The network is further consolidated by C-H center dot center dot center dot pi interactions. |
|---|