Dichlorido(4-methoxy-2-{ 2-(piperazin-4-ium-1-yl)ethyl iminomethyl}pheno late)cadmium
In the title compound, [CdCl2(C14H21N3O2)], the Schiff base ligand chelates the Cd-II ion in an N,N,O-tridentate fashion. Two Cl atoms complete a distorted square-pyramidal coordination environment around the metal atom. In the crystal, adjacent molecules are linked through C-H center dot center dot...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5202/1/Salga-2011-Dichlorido%284-methoxy.pdf http://eprints.um.edu.my/5202/ http://journals.iucr.org/e/issues/2011/07/00/issconts.html http://dx.doi.org/10.1107/s1600536811022100 |
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| Summary: | In the title compound, [CdCl2(C14H21N3O2)], the Schiff base ligand chelates the Cd-II ion in an N,N,O-tridentate fashion. Two Cl atoms complete a distorted square-pyramidal coordination environment around the metal atom. In the crystal, adjacent molecules are linked through C-H center dot center dot center dot pi interactions into infinite chains along the a axis. The molecules are further connected into a three-dimensional network via N-H center dot center dot center dot O, N-H center dot center dot center dot Cl and C-H center dot center dot center dot Cl interactions. The ethylene group is disordered over two sets of sites in a 0.520 (10):0.480 (10) ratio. |
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