Organotin(IV) complexes of 2-hydroxyacetophenone-N(4)-cyclohexylthiosemicarbazone (H(2)dact): synthesis, spectral characterization, crystal structure and biological studies

• Main Authors: Affan, M.A., Salam, M.A., Ahmad, F.B., White, Fraser, Ali, Hapipah Mohd
• Format: Article
• Published: Elsevier 2012
• Subjects: QD Chemistry
• Online Access: http://eprints.um.edu.my/5155/; http://www.sciencedirect.com/science/article/pii/S0020169312000217; http://doi.org/10.1016/j.ica.2012.01.020

Four new organotin(IV) complexes of the type [MeSnCl(dact)] (2), [BuSnCl(dact)] (3), [PhSnCl(dact)] (4) and [Ph2Sn(dact)] (5) were synthesized by the direct reaction of 2-hydroxyacetophenone-N(4)-cyclohexylthiosemicarbazone [H(2)dact, (1)] and organotin(IV) chloride(s) in absolute methanol. The liga...