Design of proton conducting solid biopolymer blend electrolytes based on chitosan-potato starch biopolymers: Deep approaches to structural and ion relaxation dynamics of H+ ion

• Main Authors: Abdulwahid, Rebar T., Aziz, Shujahadeen Bakr, Abdul Kadir, Mohd Fakhrul Zamani
• Format: Article
• Published: Wiley 2022
• Subjects: QC Physics
• Online Access: http://eprints.um.edu.my/41412/

The need for flexible energy storage devices for advanced technologies has encouraged researchers to focus on environmental-friendly biopolymers. In this work, chitosan (CS) and potato starch (PS) biopolymers are blended to prepare proton conducting solid electrolytes. Based on the X-ray diffraction (XRD) inspection, the most amorphous blended film with the lowest crystallinity degree was selected to prepare polymer electrolytes. The variation in Fourier-transform infrared spectroscopy (FTIR) bands were used to investigate the occurrence of interactions among the ammonium thiocyanate (NH4SCN) salt and CS:PS polymer blends. The experimental results of electrochemical impedance spectroscopy (EIS) were simulated with electrical equivalent circuit (EEC) modeling to determine the circuit elements. The highest value of 1.07x10-5$$ 1.07\textbackslashtimes {10}<\^>{-5} $$ S cm(-1) was recorded for the sample included 40 wt.% of dopant salt. The dielectric analyses were helpful in separating the regions ascribed to electrode and molecular polarizations. The combination of circuit elements achieved from the EEC modeling and Koops phenomenological interpretation is used to understand the behavior of the loss tangent (tan delta) pattern. The AC conductivity pattern followed Jonscher's power law. The relaxation dynamics interrelated with ions is explained using electric modulus approaches. The peaks hidden in the dielectric loss (epsilon `'$$ {\textbackslashvarepsilon}<\^>{\textbackslashprime \textbackslashprime } $$) spectra, were manifested in the imaginary part of electric modulus (M `'$$ {M}<\^>{\textbackslashprime \textbackslashprime } $$) pattern. The M `$$ {M}<\^>{\textbackslashprime } $$-M `'$$ {M}<\^>{\textbackslashprime \textbackslashprime } $$ patterns were used to shed light on the coupling between ionic motion and polymer chain dyna