Evaluation of crosslinking effect on thermo-mechanical, acoustic insulation and water absorption performance of biomass-derived cellulose cryogels

Cellulose cryogels crosslinked with epichlorohydrin (ECH) were successfully developed from kenaf core biomass via green urea/alkaline solvent system. The effect of ECH concentration (from 3 to 9 wt%) on the pore structure, density, morphology, thermal stability, mechanical properties, water absorpti...

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Main Authors: Moosavi, Seyedehmaryam, Gan, Sinyee, Chia, Chin Hua, Zakaria, Sarani
Format: Article
Published: Springer 2020
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Online Access:http://eprints.um.edu.my/36889/
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spelling my.um.eprints.368892024-11-06T03:22:40Z http://eprints.um.edu.my/36889/ Evaluation of crosslinking effect on thermo-mechanical, acoustic insulation and water absorption performance of biomass-derived cellulose cryogels Moosavi, Seyedehmaryam Gan, Sinyee Chia, Chin Hua Zakaria, Sarani Q Science (General) Cellulose cryogels crosslinked with epichlorohydrin (ECH) were successfully developed from kenaf core biomass via green urea/alkaline solvent system. The effect of ECH concentration (from 3 to 9 wt%) on the pore structure, density, morphology, thermal stability, mechanical properties, water absorption performance and acoustic insulation of cellulose cryogels were studied. It was found that the introduction of ECH affected the porosity and pore volume as well as density and water absorption of cryogels. The increase percentage of ECH has delayed the thermal decomposition of the cellulose cryogels thereby improving their thermal stability. Moreover, the compress stress and the sound absorption coefficient of the cellulose cryogels were enhanced significantly by about 50% and 27%, respectively. This work provides a facile approach to produce cost-effective biomass-derived cellulose cryogels with improved mechanical and thermal stability properties as well as acoustic insulation for preliminary studies of industrial applications. Springer 2020-04 Article PeerReviewed Moosavi, Seyedehmaryam and Gan, Sinyee and Chia, Chin Hua and Zakaria, Sarani (2020) Evaluation of crosslinking effect on thermo-mechanical, acoustic insulation and water absorption performance of biomass-derived cellulose cryogels. Journal of Polymers and the Environment, 28 (4). pp. 1180-1189. ISSN 1566-2543, DOI https://doi.org/10.1007/s10924-020-01676-0 <https://doi.org/10.1007/s10924-020-01676-0>. 10.1007/s10924-020-01676-0
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Moosavi, Seyedehmaryam
Gan, Sinyee
Chia, Chin Hua
Zakaria, Sarani
Evaluation of crosslinking effect on thermo-mechanical, acoustic insulation and water absorption performance of biomass-derived cellulose cryogels
description Cellulose cryogels crosslinked with epichlorohydrin (ECH) were successfully developed from kenaf core biomass via green urea/alkaline solvent system. The effect of ECH concentration (from 3 to 9 wt%) on the pore structure, density, morphology, thermal stability, mechanical properties, water absorption performance and acoustic insulation of cellulose cryogels were studied. It was found that the introduction of ECH affected the porosity and pore volume as well as density and water absorption of cryogels. The increase percentage of ECH has delayed the thermal decomposition of the cellulose cryogels thereby improving their thermal stability. Moreover, the compress stress and the sound absorption coefficient of the cellulose cryogels were enhanced significantly by about 50% and 27%, respectively. This work provides a facile approach to produce cost-effective biomass-derived cellulose cryogels with improved mechanical and thermal stability properties as well as acoustic insulation for preliminary studies of industrial applications.
format Article
author Moosavi, Seyedehmaryam
Gan, Sinyee
Chia, Chin Hua
Zakaria, Sarani
author_facet Moosavi, Seyedehmaryam
Gan, Sinyee
Chia, Chin Hua
Zakaria, Sarani
author_sort Moosavi, Seyedehmaryam
title Evaluation of crosslinking effect on thermo-mechanical, acoustic insulation and water absorption performance of biomass-derived cellulose cryogels
title_short Evaluation of crosslinking effect on thermo-mechanical, acoustic insulation and water absorption performance of biomass-derived cellulose cryogels
title_full Evaluation of crosslinking effect on thermo-mechanical, acoustic insulation and water absorption performance of biomass-derived cellulose cryogels
title_fullStr Evaluation of crosslinking effect on thermo-mechanical, acoustic insulation and water absorption performance of biomass-derived cellulose cryogels
title_full_unstemmed Evaluation of crosslinking effect on thermo-mechanical, acoustic insulation and water absorption performance of biomass-derived cellulose cryogels
title_sort evaluation of crosslinking effect on thermo-mechanical, acoustic insulation and water absorption performance of biomass-derived cellulose cryogels
publisher Springer
publishDate 2020
url http://eprints.um.edu.my/36889/
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score 13.214268