Vortex assisted dispersive liquid-liquid microextraction based on low transition temperature mixture solvent for the HPLC determination of pyrethroids in water samples: Experimental study and COSMO-RS

A green, simple, and effective vortex-assisted dispersive liquid-liquid microextraction method that utilizes a menthol-based low transition temperature mixture (menthol-LTTM-VADLLME) was developed to extract and preconcentrate four types of pyrethroids, namely bifenthrin, deltamethrin, fenpropathrin...

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Main Authors: Hussin, Siti Amira Mat, Varanusupakul, Pakorn, Kassim, Mohd Azlan, Rozi, Siti Khalijah Mahmad, Mohamad, Sharifah
Format: Article
Published: Elsevier 2021
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Online Access:http://eprints.um.edu.my/28116/
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spelling my.um.eprints.281162022-07-25T08:12:03Z http://eprints.um.edu.my/28116/ Vortex assisted dispersive liquid-liquid microextraction based on low transition temperature mixture solvent for the HPLC determination of pyrethroids in water samples: Experimental study and COSMO-RS Hussin, Siti Amira Mat Varanusupakul, Pakorn Kassim, Mohd Azlan Rozi, Siti Khalijah Mahmad Mohamad, Sharifah QD Chemistry A green, simple, and effective vortex-assisted dispersive liquid-liquid microextraction method that utilizes a menthol-based low transition temperature mixture (menthol-LTTM-VADLLME) was developed to extract and preconcentrate four types of pyrethroids, namely bifenthrin, deltamethrin, fenpropathrin, and permethrin from water samples. In addition, quantum chemical-based conductor-like screening model for realistic solvents (COSMO-RS) software was used to predict the molecular interaction between low transition temperature mixtures (LTTMs) and pyrethroids based on their sigma-profile, sigma-potentials, and activity coefficient at infinite dilution. High performance liquid chromatography (HPLC) was employed for the further separation of the pyrethroids and their quantification. Several key parameters that affect pyrethroid extraction efficiency are identified as the vortex time, type of LTTM, volume of LTTM, type of dispersive solvent, dispersive solvent volume, type of salt, and amount of salt. The extraction time of 90 s and 150 mu L of menthol: sesamol at ratio 1:1 were selected as the best conditions, while ionic strength and type of dispersant solvent were not relevant for the extraction of the target compounds. After optimization, the menthol-LTTM-VADLLME method was found to be able to detect pyrethroids in the range of 0.5-1000.0 mu g/L with good linearity (correlation coefficient = 0.9988-0.9995). The method detection limit and quantification limit were found to be in the range of 0.05-0.11 mu g/L and 0.18-0.35 mu g/L, respectively. The relative standard deviation of inter-day and intra-day precisions were 2.2-5.0% (n = 5) and 1.2-1.9% (n = 7) respectively. The optimized method can successively determine pyrethroids in tap, drinking and river water samples with good recoveries of 73-111%. Hence, this method presents a good approach for determining pyrethroid content in water samples. Elsevier 2021-12 Article PeerReviewed Hussin, Siti Amira Mat and Varanusupakul, Pakorn and Kassim, Mohd Azlan and Rozi, Siti Khalijah Mahmad and Mohamad, Sharifah (2021) Vortex assisted dispersive liquid-liquid microextraction based on low transition temperature mixture solvent for the HPLC determination of pyrethroids in water samples: Experimental study and COSMO-RS. Microchemical Journal, 171. ISSN 0026-265X, DOI https://doi.org/10.1016/j.microc.2021.106780 <https://doi.org/10.1016/j.microc.2021.106780>. 10.1016/j.microc.2021.106780
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QD Chemistry
spellingShingle QD Chemistry
Hussin, Siti Amira Mat
Varanusupakul, Pakorn
Kassim, Mohd Azlan
Rozi, Siti Khalijah Mahmad
Mohamad, Sharifah
Vortex assisted dispersive liquid-liquid microextraction based on low transition temperature mixture solvent for the HPLC determination of pyrethroids in water samples: Experimental study and COSMO-RS
description A green, simple, and effective vortex-assisted dispersive liquid-liquid microextraction method that utilizes a menthol-based low transition temperature mixture (menthol-LTTM-VADLLME) was developed to extract and preconcentrate four types of pyrethroids, namely bifenthrin, deltamethrin, fenpropathrin, and permethrin from water samples. In addition, quantum chemical-based conductor-like screening model for realistic solvents (COSMO-RS) software was used to predict the molecular interaction between low transition temperature mixtures (LTTMs) and pyrethroids based on their sigma-profile, sigma-potentials, and activity coefficient at infinite dilution. High performance liquid chromatography (HPLC) was employed for the further separation of the pyrethroids and their quantification. Several key parameters that affect pyrethroid extraction efficiency are identified as the vortex time, type of LTTM, volume of LTTM, type of dispersive solvent, dispersive solvent volume, type of salt, and amount of salt. The extraction time of 90 s and 150 mu L of menthol: sesamol at ratio 1:1 were selected as the best conditions, while ionic strength and type of dispersant solvent were not relevant for the extraction of the target compounds. After optimization, the menthol-LTTM-VADLLME method was found to be able to detect pyrethroids in the range of 0.5-1000.0 mu g/L with good linearity (correlation coefficient = 0.9988-0.9995). The method detection limit and quantification limit were found to be in the range of 0.05-0.11 mu g/L and 0.18-0.35 mu g/L, respectively. The relative standard deviation of inter-day and intra-day precisions were 2.2-5.0% (n = 5) and 1.2-1.9% (n = 7) respectively. The optimized method can successively determine pyrethroids in tap, drinking and river water samples with good recoveries of 73-111%. Hence, this method presents a good approach for determining pyrethroid content in water samples.
format Article
author Hussin, Siti Amira Mat
Varanusupakul, Pakorn
Kassim, Mohd Azlan
Rozi, Siti Khalijah Mahmad
Mohamad, Sharifah
author_facet Hussin, Siti Amira Mat
Varanusupakul, Pakorn
Kassim, Mohd Azlan
Rozi, Siti Khalijah Mahmad
Mohamad, Sharifah
author_sort Hussin, Siti Amira Mat
title Vortex assisted dispersive liquid-liquid microextraction based on low transition temperature mixture solvent for the HPLC determination of pyrethroids in water samples: Experimental study and COSMO-RS
title_short Vortex assisted dispersive liquid-liquid microextraction based on low transition temperature mixture solvent for the HPLC determination of pyrethroids in water samples: Experimental study and COSMO-RS
title_full Vortex assisted dispersive liquid-liquid microextraction based on low transition temperature mixture solvent for the HPLC determination of pyrethroids in water samples: Experimental study and COSMO-RS
title_fullStr Vortex assisted dispersive liquid-liquid microextraction based on low transition temperature mixture solvent for the HPLC determination of pyrethroids in water samples: Experimental study and COSMO-RS
title_full_unstemmed Vortex assisted dispersive liquid-liquid microextraction based on low transition temperature mixture solvent for the HPLC determination of pyrethroids in water samples: Experimental study and COSMO-RS
title_sort vortex assisted dispersive liquid-liquid microextraction based on low transition temperature mixture solvent for the hplc determination of pyrethroids in water samples: experimental study and cosmo-rs
publisher Elsevier
publishDate 2021
url http://eprints.um.edu.my/28116/
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score 13.18916