Synthesis, characterization, and a study of the influence of HSO4](-) and SO4](2-) on thermal phase transition and thermal stability of two new organic acid salts containing dication cyclic amine
Two new organic acid salts were synthesized, and their chemical structures were elucidated by various spectroscopy analyses including infra-red, one and two dimensions of nuclear magnetic resonance, and mass spectroscopy. The pH and thermal behavior and thermal stability displayed different acidity...
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my.um.eprints.266692022-04-07T03:17:43Z http://eprints.um.edu.my/26669/ Synthesis, characterization, and a study of the influence of HSO4](-) and SO4](2-) on thermal phase transition and thermal stability of two new organic acid salts containing dication cyclic amine Zaharani, Lia Shahnavaz, Zohreh Johan, Mohd Rafie Khaligh, Nader Ghaffari QC Physics QD Chemistry Two new organic acid salts were synthesized, and their chemical structures were elucidated by various spectroscopy analyses including infra-red, one and two dimensions of nuclear magnetic resonance, and mass spectroscopy. The pH and thermal behavior and thermal stability displayed different acidity and stability which approved the existence of different chemical structures for two acid salts containing the same dication i.e., 4,4'-trimethylene-N,N'-dipiperidinium and two different anions of sulfate and hydrogensulfate. Although H-1 NMR did not show acid proton of HSO4](-), the FTIR spectra of acid salts act as key support to approve of their chemical structures. The thermal behavior and thermal stability of two as-synthesized acid salts were mainly different. This fact indicates various electrostatic and hydrogen-bonding interactions, which in turn, is further supports their proposed chemical structures. (C) 2021 Elsevier B.V. All rights reserved. Elsevier 2021-08-15 Article PeerReviewed Zaharani, Lia and Shahnavaz, Zohreh and Johan, Mohd Rafie and Khaligh, Nader Ghaffari (2021) Synthesis, characterization, and a study of the influence of HSO4](-) and SO4](2-) on thermal phase transition and thermal stability of two new organic acid salts containing dication cyclic amine. Journal of Molecular Liquids, 336. ISSN 0167-7322, DOI https://doi.org/10.1016/j.molliq.2021.116856 <https://doi.org/10.1016/j.molliq.2021.116856>. 10.1016/j.molliq.2021.116856 |
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QC Physics QD Chemistry Zaharani, Lia Shahnavaz, Zohreh Johan, Mohd Rafie Khaligh, Nader Ghaffari Synthesis, characterization, and a study of the influence of HSO4](-) and SO4](2-) on thermal phase transition and thermal stability of two new organic acid salts containing dication cyclic amine |
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Two new organic acid salts were synthesized, and their chemical structures were elucidated by various spectroscopy analyses including infra-red, one and two dimensions of nuclear magnetic resonance, and mass spectroscopy. The pH and thermal behavior and thermal stability displayed different acidity and stability which approved the existence of different chemical structures for two acid salts containing the same dication i.e., 4,4'-trimethylene-N,N'-dipiperidinium and two different anions of sulfate and hydrogensulfate. Although H-1 NMR did not show acid proton of HSO4](-), the FTIR spectra of acid salts act as key support to approve of their chemical structures. The thermal behavior and thermal stability of two as-synthesized acid salts were mainly different. This fact indicates various electrostatic and hydrogen-bonding interactions, which in turn, is further supports their proposed chemical structures. (C) 2021 Elsevier B.V. All rights reserved. |
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Article |
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Zaharani, Lia Shahnavaz, Zohreh Johan, Mohd Rafie Khaligh, Nader Ghaffari |
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Zaharani, Lia Shahnavaz, Zohreh Johan, Mohd Rafie Khaligh, Nader Ghaffari |
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Zaharani, Lia |
title |
Synthesis, characterization, and a study of the influence of HSO4](-) and SO4](2-) on thermal phase transition and thermal stability of two new organic acid salts containing dication cyclic amine |
title_short |
Synthesis, characterization, and a study of the influence of HSO4](-) and SO4](2-) on thermal phase transition and thermal stability of two new organic acid salts containing dication cyclic amine |
title_full |
Synthesis, characterization, and a study of the influence of HSO4](-) and SO4](2-) on thermal phase transition and thermal stability of two new organic acid salts containing dication cyclic amine |
title_fullStr |
Synthesis, characterization, and a study of the influence of HSO4](-) and SO4](2-) on thermal phase transition and thermal stability of two new organic acid salts containing dication cyclic amine |
title_full_unstemmed |
Synthesis, characterization, and a study of the influence of HSO4](-) and SO4](2-) on thermal phase transition and thermal stability of two new organic acid salts containing dication cyclic amine |
title_sort |
synthesis, characterization, and a study of the influence of hso4](-) and so4](2-) on thermal phase transition and thermal stability of two new organic acid salts containing dication cyclic amine |
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Elsevier |
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2021 |
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http://eprints.um.edu.my/26669/ |
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