Bis(quinolin-8-olato-κ2N,O)lead(II)

The PbII atom in the title compound, [Pb(C9H 6NO)2], is N,O-chelated by two organic ligands, and two molecules are linked across a centre of inversion to form a dinuclear entity. These dinuclear entities are linked by somewhat weaker Pb⋯O bonds into a chain. There are two independent molecules in th...

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Main Authors: Zhu, Li-Hong, Zeng, Ming-Hua, Ng, Seik Weng
Format: Article
Published: International Union of Crystallography 2005
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Online Access:http://eprints.um.edu.my/25280/
https://doi.org/10.1107/S1600536805011852
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spelling my.um.eprints.252802020-08-06T06:21:49Z http://eprints.um.edu.my/25280/ Bis(quinolin-8-olato-κ2N,O)lead(II) Zhu, Li-Hong Zeng, Ming-Hua Ng, Seik Weng Q Science (General) QD Chemistry The PbII atom in the title compound, [Pb(C9H 6NO)2], is N,O-chelated by two organic ligands, and two molecules are linked across a centre of inversion to form a dinuclear entity. These dinuclear entities are linked by somewhat weaker Pb⋯O bonds into a chain. There are two independent molecules in the asymmetric unit with similar geometry around the Pb atoms, which have a pseudo-pentagonal-bipyramidal coordination with one of the axial positions occupied by the Pb lone pair. Some distances involving the Pb atoms are significantly different between the two molecules. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved. International Union of Crystallography 2005 Article PeerReviewed Zhu, Li-Hong and Zeng, Ming-Hua and Ng, Seik Weng (2005) Bis(quinolin-8-olato-κ2N,O)lead(II). Acta Crystallographica Section E: Structure Reports Online, 61 (6). m1082-m1084. ISSN 1600-5368 https://doi.org/10.1107/S1600536805011852 doi:10.1107/S1600536805011852
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
Zhu, Li-Hong
Zeng, Ming-Hua
Ng, Seik Weng
Bis(quinolin-8-olato-κ2N,O)lead(II)
description The PbII atom in the title compound, [Pb(C9H 6NO)2], is N,O-chelated by two organic ligands, and two molecules are linked across a centre of inversion to form a dinuclear entity. These dinuclear entities are linked by somewhat weaker Pb⋯O bonds into a chain. There are two independent molecules in the asymmetric unit with similar geometry around the Pb atoms, which have a pseudo-pentagonal-bipyramidal coordination with one of the axial positions occupied by the Pb lone pair. Some distances involving the Pb atoms are significantly different between the two molecules. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved.
format Article
author Zhu, Li-Hong
Zeng, Ming-Hua
Ng, Seik Weng
author_facet Zhu, Li-Hong
Zeng, Ming-Hua
Ng, Seik Weng
author_sort Zhu, Li-Hong
title Bis(quinolin-8-olato-κ2N,O)lead(II)
title_short Bis(quinolin-8-olato-κ2N,O)lead(II)
title_full Bis(quinolin-8-olato-κ2N,O)lead(II)
title_fullStr Bis(quinolin-8-olato-κ2N,O)lead(II)
title_full_unstemmed Bis(quinolin-8-olato-κ2N,O)lead(II)
title_sort bis(quinolin-8-olato-κ2n,o)lead(ii)
publisher International Union of Crystallography
publishDate 2005
url http://eprints.um.edu.my/25280/
https://doi.org/10.1107/S1600536805011852
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score 13.160551