Diaquabis(1,10-phenanthroline-κ2N,N′)zinc(II) 2-hydroxy-5-sulfonatobenzoate tetrahydrate
The water-coordinated metal centre in the title salt, [Zn(C12H8N2)2(H2O)2] C7H4O6S·4H2O, is chelated by the two bidentate N-heterocycles, leading to an overall distorted octa-hedral environment. The cation, dianion and solvent water mol-ecules inter-act by O - H⋯O hydrogen bonds to form a layer moti...
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| Main Authors: | , , |
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| Format: | Article |
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International Union of Crystallography
2009
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/25148/ https://doi.org/10.1107/S1600536809003055 |
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| Summary: | The water-coordinated metal centre in the title salt, [Zn(C12H8N2)2(H2O)2] C7H4O6S·4H2O, is chelated by the two bidentate N-heterocycles, leading to an overall distorted octa-hedral environment. The cation, dianion and solvent water mol-ecules inter-act by O - H⋯O hydrogen bonds to form a layer motif. The SO3 group is disordered over two positions with respect to the O atoms in a 0.76 (1):0.24 (1) ratio. One of the solvent water molecules is also disordered over two positions in a 0.56 (4):0.44 (4) ratio. |
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