Synthesis and characterization of an energetic three-dimensional metal–organic framework with blue photoluminescence
A new inorganic-organic hybrid lead(II) coordination polymer [PbCl(tza)]n (Htza = tetrazole-1-acetic acid) has been synthesized under hydrothermal condition. The complex was characterized by elemental analysis, FT-IR spectroscopy, single-crystal X-ray analysis, thermogravimetric analysis (TG) and di...
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my.um.eprints.250972020-07-13T08:32:00Z http://eprints.um.edu.my/25097/ Synthesis and characterization of an energetic three-dimensional metal–organic framework with blue photoluminescence Zhang, Kou-Lin Pan, Zi-Cai Chang, Yan Liu, Wen-Long Ng, Seik Weng Q Science (General) QD Chemistry A new inorganic-organic hybrid lead(II) coordination polymer [PbCl(tza)]n (Htza = tetrazole-1-acetic acid) has been synthesized under hydrothermal condition. The complex was characterized by elemental analysis, FT-IR spectroscopy, single-crystal X-ray analysis, thermogravimetric analysis (TG) and differential scanning calorimetry thermal analysis (DSC). The Pb(II) centers are connected through both the tza and Cl- bridging ligands to form a three-dimensional metal-organic framework (MOF). The compound has been found to exhibit blue photoluminescence in the solid state at room temperature and may be good candidates for photoactive materials. DSC thermal analysis shows the complex is an energetic coordination compound and tza can be used as an energetic ligand. © 2009 Elsevier B.V. All rights reserved. Elsevier 2009 Article PeerReviewed Zhang, Kou-Lin and Pan, Zi-Cai and Chang, Yan and Liu, Wen-Long and Ng, Seik Weng (2009) Synthesis and characterization of an energetic three-dimensional metal–organic framework with blue photoluminescence. Materials Letters, 63 (24-25). pp. 2136-2138. ISSN 0167-577X https://doi.org/10.1016/j.matlet.2009.05.040 doi:10.1016/j.matlet.2009.05.040 |
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Q Science (General) QD Chemistry Zhang, Kou-Lin Pan, Zi-Cai Chang, Yan Liu, Wen-Long Ng, Seik Weng Synthesis and characterization of an energetic three-dimensional metal–organic framework with blue photoluminescence |
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A new inorganic-organic hybrid lead(II) coordination polymer [PbCl(tza)]n (Htza = tetrazole-1-acetic acid) has been synthesized under hydrothermal condition. The complex was characterized by elemental analysis, FT-IR spectroscopy, single-crystal X-ray analysis, thermogravimetric analysis (TG) and differential scanning calorimetry thermal analysis (DSC). The Pb(II) centers are connected through both the tza and Cl- bridging ligands to form a three-dimensional metal-organic framework (MOF). The compound has been found to exhibit blue photoluminescence in the solid state at room temperature and may be good candidates for photoactive materials. DSC thermal analysis shows the complex is an energetic coordination compound and tza can be used as an energetic ligand. © 2009 Elsevier B.V. All rights reserved. |
format |
Article |
author |
Zhang, Kou-Lin Pan, Zi-Cai Chang, Yan Liu, Wen-Long Ng, Seik Weng |
author_facet |
Zhang, Kou-Lin Pan, Zi-Cai Chang, Yan Liu, Wen-Long Ng, Seik Weng |
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Zhang, Kou-Lin |
title |
Synthesis and characterization of an energetic three-dimensional metal–organic framework with blue photoluminescence |
title_short |
Synthesis and characterization of an energetic three-dimensional metal–organic framework with blue photoluminescence |
title_full |
Synthesis and characterization of an energetic three-dimensional metal–organic framework with blue photoluminescence |
title_fullStr |
Synthesis and characterization of an energetic three-dimensional metal–organic framework with blue photoluminescence |
title_full_unstemmed |
Synthesis and characterization of an energetic three-dimensional metal–organic framework with blue photoluminescence |
title_sort |
synthesis and characterization of an energetic three-dimensional metal–organic framework with blue photoluminescence |
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Elsevier |
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2009 |
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http://eprints.um.edu.my/25097/ https://doi.org/10.1016/j.matlet.2009.05.040 |
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