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Poly[[μ4-tartrato-cadmium(II)] 0.167-hydrate]

The title compound, {[Cd(C4H4O6)] ·0.167H2O}n, adopts a three-dimensional network structure in which each CdII ion is chelated by two pairs of carboxyl-ate and hydroxyl O atoms from two tartrate anions, and is additionally linked to two O atoms of two carboxyl-ate groups that are not involved in che...

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Main Authors: Zhao, Li-Zhen, Li, Ping, Cao, Bao-Liang, Ng, Seik Weng
Format: Article
Published: International Union of Crystallography 2009
Subjects:
Q Science (General)
QD Chemistry
Online Access:http://eprints.um.edu.my/25094/
https://doi.org/10.1107/S1600536809016882
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spelling my.um.eprints.250942020-07-13T08:26:13Z http://eprints.um.edu.my/25094/ Poly[[μ4-tartrato-cadmium(II)] 0.167-hydrate] Zhao, Li-Zhen Li, Ping Cao, Bao-Liang Ng, Seik Weng Q Science (General) QD Chemistry The title compound, {[Cd(C4H4O6)] ·0.167H2O}n, adopts a three-dimensional network structure in which each CdII ion is chelated by two pairs of carboxyl-ate and hydroxyl O atoms from two tartrate anions, and is additionally linked to two O atoms of two carboxyl-ate groups that are not involved in chelation. The asymmetric unit has four independent cadmium atoms, two of which lie on special positions of 2 site symmetry. The tartrate anions all lie on general positions. All hydroxyl groups are engaged in O - H⋯O hydrogen-bonds, one of which is also bifurcated. The non-coordinating water molecule is situated on a site with half-occupation. International Union of Crystallography 2009 Article PeerReviewed Zhao, Li-Zhen and Li, Ping and Cao, Bao-Liang and Ng, Seik Weng (2009) Poly[[μ4-tartrato-cadmium(II)] 0.167-hydrate]. Acta Crystallographica Section E: Structure Reports Online, 65 (6). m629-m629. ISSN 1600-5368 https://doi.org/10.1107/S1600536809016882 doi:10.1107/S1600536809016882
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
Zhao, Li-Zhen
Li, Ping
Cao, Bao-Liang
Ng, Seik Weng
Poly[[μ4-tartrato-cadmium(II)] 0.167-hydrate]
description The title compound, {[Cd(C4H4O6)] ·0.167H2O}n, adopts a three-dimensional network structure in which each CdII ion is chelated by two pairs of carboxyl-ate and hydroxyl O atoms from two tartrate anions, and is additionally linked to two O atoms of two carboxyl-ate groups that are not involved in chelation. The asymmetric unit has four independent cadmium atoms, two of which lie on special positions of 2 site symmetry. The tartrate anions all lie on general positions. All hydroxyl groups are engaged in O - H⋯O hydrogen-bonds, one of which is also bifurcated. The non-coordinating water molecule is situated on a site with half-occupation.
format Article
author Zhao, Li-Zhen
Li, Ping
Cao, Bao-Liang
Ng, Seik Weng
author_facet Zhao, Li-Zhen
Li, Ping
Cao, Bao-Liang
Ng, Seik Weng
author_sort Zhao, Li-Zhen
title Poly[[μ4-tartrato-cadmium(II)] 0.167-hydrate]
title_short Poly[[μ4-tartrato-cadmium(II)] 0.167-hydrate]
title_full Poly[[μ4-tartrato-cadmium(II)] 0.167-hydrate]
title_fullStr Poly[[μ4-tartrato-cadmium(II)] 0.167-hydrate]
title_full_unstemmed Poly[[μ4-tartrato-cadmium(II)] 0.167-hydrate]
title_sort poly[[μ4-tartrato-cadmium(ii)] 0.167-hydrate]
publisher International Union of Crystallography
publishDate 2009
url http://eprints.um.edu.my/25094/
https://doi.org/10.1107/S1600536809016882
_version_ 1680856999189807104
score 13.160551

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