The structure elucidation of new mono-core dicationic salt-containing chlorosulfonate counterion: Raman study of a pure sample of chlorosulfonate anion in the solid and liquid state
This paper presents the design and synthesis of new ionic liquid containing dication of 1H,4H-piperazine-diium ring and two chlorosulfonate as counterions. The structure elucidation of new ionic organo-compound was performed by 1D and 2D NMR, FTIR, Raman, and mass spectrum. Then, the correct structu...
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my.um.eprints.246262020-06-04T00:47:53Z http://eprints.um.edu.my/24626/ The structure elucidation of new mono-core dicationic salt-containing chlorosulfonate counterion: Raman study of a pure sample of chlorosulfonate anion in the solid and liquid state Zaharani, Lia Khaligh, Nader Ghaffari Shahnavaz, Zohreh Johan, Mohd Rafie TK Electrical engineering. Electronics Nuclear engineering This paper presents the design and synthesis of new ionic liquid containing dication of 1H,4H-piperazine-diium ring and two chlorosulfonate as counterions. The structure elucidation of new ionic organo-compound was performed by 1D and 2D NMR, FTIR, Raman, and mass spectrum. Then, the correct structure was elucidated by COSY which was supported by Raman study. IR and Raman spectra of liquid and solid-state of 1H,4H-piperazine-diium dichlorosulfonate are studied. Assignments are made for FTIR and Raman peaks, and our results are compared with previous reports in the literature. © 2020 Elsevier B.V. Elsevier 2020 Article PeerReviewed Zaharani, Lia and Khaligh, Nader Ghaffari and Shahnavaz, Zohreh and Johan, Mohd Rafie (2020) The structure elucidation of new mono-core dicationic salt-containing chlorosulfonate counterion: Raman study of a pure sample of chlorosulfonate anion in the solid and liquid state. Journal of Molecular Structure, 1216. p. 128182. ISSN 0022-2860 https://doi.org/10.1016/j.molstruc.2020.128182 doi:10.1016/j.molstruc.2020.128182 |
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TK Electrical engineering. Electronics Nuclear engineering Zaharani, Lia Khaligh, Nader Ghaffari Shahnavaz, Zohreh Johan, Mohd Rafie The structure elucidation of new mono-core dicationic salt-containing chlorosulfonate counterion: Raman study of a pure sample of chlorosulfonate anion in the solid and liquid state |
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This paper presents the design and synthesis of new ionic liquid containing dication of 1H,4H-piperazine-diium ring and two chlorosulfonate as counterions. The structure elucidation of new ionic organo-compound was performed by 1D and 2D NMR, FTIR, Raman, and mass spectrum. Then, the correct structure was elucidated by COSY which was supported by Raman study. IR and Raman spectra of liquid and solid-state of 1H,4H-piperazine-diium dichlorosulfonate are studied. Assignments are made for FTIR and Raman peaks, and our results are compared with previous reports in the literature. © 2020 Elsevier B.V. |
format |
Article |
author |
Zaharani, Lia Khaligh, Nader Ghaffari Shahnavaz, Zohreh Johan, Mohd Rafie |
author_facet |
Zaharani, Lia Khaligh, Nader Ghaffari Shahnavaz, Zohreh Johan, Mohd Rafie |
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Zaharani, Lia |
title |
The structure elucidation of new mono-core dicationic salt-containing chlorosulfonate counterion: Raman study of a pure sample of chlorosulfonate anion in the solid and liquid state |
title_short |
The structure elucidation of new mono-core dicationic salt-containing chlorosulfonate counterion: Raman study of a pure sample of chlorosulfonate anion in the solid and liquid state |
title_full |
The structure elucidation of new mono-core dicationic salt-containing chlorosulfonate counterion: Raman study of a pure sample of chlorosulfonate anion in the solid and liquid state |
title_fullStr |
The structure elucidation of new mono-core dicationic salt-containing chlorosulfonate counterion: Raman study of a pure sample of chlorosulfonate anion in the solid and liquid state |
title_full_unstemmed |
The structure elucidation of new mono-core dicationic salt-containing chlorosulfonate counterion: Raman study of a pure sample of chlorosulfonate anion in the solid and liquid state |
title_sort |
structure elucidation of new mono-core dicationic salt-containing chlorosulfonate counterion: raman study of a pure sample of chlorosulfonate anion in the solid and liquid state |
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Elsevier |
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2020 |
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http://eprints.um.edu.my/24626/ https://doi.org/10.1016/j.molstruc.2020.128182 |
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1669008007113998336 |
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