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Hydrolysis products of dibutyltin dichlorides

The hydrolysis of di-s-butyltin dichloride yields similar products to those found for the di-n-butyl compound whereas the hydrolysis behaviour of di-t-butyltin dichloride is markedly different. Distannoxanes are not found in the latter case but instead di-t-butyltin hydroxide chloride is obtained. U...

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Main Authors: Chua, C.K., Murray, J.D.
Format: Article
Published: Royal Society of Chemistry 1971
Subjects:
Q Science (General)
QD Chemistry
Online Access:http://eprints.um.edu.my/24468/
https://doi.org/10.1039/J19710000360
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spelling my.um.eprints.244682021-03-24T04:28:15Z http://eprints.um.edu.my/24468/ Hydrolysis products of dibutyltin dichlorides Chua, C.K. Murray, J.D. Q Science (General) QD Chemistry The hydrolysis of di-s-butyltin dichloride yields similar products to those found for the di-n-butyl compound whereas the hydrolysis behaviour of di-t-butyltin dichloride is markedly different. Distannoxanes are not found in the latter case but instead di-t-butyltin hydroxide chloride is obtained. Under strongly basic conditions di-t-butyltin oxide is formed which has unusual structural properties and can easily be converted into a 'dihydroxide.' Comparative i.r. data derived from analogous systems are presented. Royal Society of Chemistry 1971 Article PeerReviewed Chua, C.K. and Murray, J.D. (1971) Hydrolysis products of dibutyltin dichlorides. Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry. pp. 360-367. ISSN 0022-4944 https://doi.org/10.1039/J19710000360 doi:10.1039/J19710000360
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
Chua, C.K.
Murray, J.D.
Hydrolysis products of dibutyltin dichlorides
description The hydrolysis of di-s-butyltin dichloride yields similar products to those found for the di-n-butyl compound whereas the hydrolysis behaviour of di-t-butyltin dichloride is markedly different. Distannoxanes are not found in the latter case but instead di-t-butyltin hydroxide chloride is obtained. Under strongly basic conditions di-t-butyltin oxide is formed which has unusual structural properties and can easily be converted into a 'dihydroxide.' Comparative i.r. data derived from analogous systems are presented.
format Article
author Chua, C.K.
Murray, J.D.
author_facet Chua, C.K.
Murray, J.D.
author_sort Chua, C.K.
title Hydrolysis products of dibutyltin dichlorides
title_short Hydrolysis products of dibutyltin dichlorides
title_full Hydrolysis products of dibutyltin dichlorides
title_fullStr Hydrolysis products of dibutyltin dichlorides
title_full_unstemmed Hydrolysis products of dibutyltin dichlorides
title_sort hydrolysis products of dibutyltin dichlorides
publisher Royal Society of Chemistry
publishDate 1971
url http://eprints.um.edu.my/24468/
https://doi.org/10.1039/J19710000360
_version_ 1695531082736205824
score 13.209306

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