Facile synthesis and characterization of novel dicarboxylate-Cu based MOFs materials
This work describes the synthesis and characterization of benzylimidazole (Bim) and piperazine (P) based metal organic framework (MOF) materials with two different linkers of adipic acid (A) and terephthalic acid (T) namely: ABim-Cu-MOF, TBim-Cu-MOF, AP-Cu-MOF, and TP-Cu-MOF. The physical and chemic...
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my.um.eprints.234642020-01-16T06:57:37Z http://eprints.um.edu.my/23464/ Facile synthesis and characterization of novel dicarboxylate-Cu based MOFs materials Sherino, Bibi Halim, Siti Nadiah Abdul Manan, Ninie Suhana Abdul Sarip, Rozie Al'Abri, Aisha Mohammed Mohamad, Sharifah Q Science (General) QD Chemistry This work describes the synthesis and characterization of benzylimidazole (Bim) and piperazine (P) based metal organic framework (MOF) materials with two different linkers of adipic acid (A) and terephthalic acid (T) namely: ABim-Cu-MOF, TBim-Cu-MOF, AP-Cu-MOF, and TP-Cu-MOF. The physical and chemical characterization of these MOF materials were studied by elemental analysis (CHN), Fourier-transform infrared spectrometry (FT-IR), powder x-ray diffraction (PXRD), BET surface area and thermogravimetric analyses. The synthesized MOF materials were used as a modifier for carbon paste electrode to study its electrochemical behaviour towards ferricyanide. The electrochemical characterization revealed that the newly synthesized MOFs offer an excellent potential as electrode modifier for the redox reaction of ferricyanide. The reaction was reversible and diffusion controlled with the calculated diffusion coefficient values in the range of (4.86 × 10−5–2.66 × 10−5 cm2 s−1). © 2019 Elsevier B.V. Elsevier 2019 Article PeerReviewed Sherino, Bibi and Halim, Siti Nadiah Abdul and Manan, Ninie Suhana Abdul and Sarip, Rozie and Al'Abri, Aisha Mohammed and Mohamad, Sharifah (2019) Facile synthesis and characterization of novel dicarboxylate-Cu based MOFs materials. Inorganica Chimica Acta, 491. pp. 59-66. ISSN 0020-1693 https://doi.org/10.1016/j.ica.2019.03.033 doi:10.1016/j.ica.2019.03.033 |
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Q Science (General) QD Chemistry Sherino, Bibi Halim, Siti Nadiah Abdul Manan, Ninie Suhana Abdul Sarip, Rozie Al'Abri, Aisha Mohammed Mohamad, Sharifah Facile synthesis and characterization of novel dicarboxylate-Cu based MOFs materials |
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This work describes the synthesis and characterization of benzylimidazole (Bim) and piperazine (P) based metal organic framework (MOF) materials with two different linkers of adipic acid (A) and terephthalic acid (T) namely: ABim-Cu-MOF, TBim-Cu-MOF, AP-Cu-MOF, and TP-Cu-MOF. The physical and chemical characterization of these MOF materials were studied by elemental analysis (CHN), Fourier-transform infrared spectrometry (FT-IR), powder x-ray diffraction (PXRD), BET surface area and thermogravimetric analyses. The synthesized MOF materials were used as a modifier for carbon paste electrode to study its electrochemical behaviour towards ferricyanide. The electrochemical characterization revealed that the newly synthesized MOFs offer an excellent potential as electrode modifier for the redox reaction of ferricyanide. The reaction was reversible and diffusion controlled with the calculated diffusion coefficient values in the range of (4.86 × 10−5–2.66 × 10−5 cm2 s−1). © 2019 Elsevier B.V. |
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Article |
author |
Sherino, Bibi Halim, Siti Nadiah Abdul Manan, Ninie Suhana Abdul Sarip, Rozie Al'Abri, Aisha Mohammed Mohamad, Sharifah |
author_facet |
Sherino, Bibi Halim, Siti Nadiah Abdul Manan, Ninie Suhana Abdul Sarip, Rozie Al'Abri, Aisha Mohammed Mohamad, Sharifah |
author_sort |
Sherino, Bibi |
title |
Facile synthesis and characterization of novel dicarboxylate-Cu based MOFs materials |
title_short |
Facile synthesis and characterization of novel dicarboxylate-Cu based MOFs materials |
title_full |
Facile synthesis and characterization of novel dicarboxylate-Cu based MOFs materials |
title_fullStr |
Facile synthesis and characterization of novel dicarboxylate-Cu based MOFs materials |
title_full_unstemmed |
Facile synthesis and characterization of novel dicarboxylate-Cu based MOFs materials |
title_sort |
facile synthesis and characterization of novel dicarboxylate-cu based mofs materials |
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Elsevier |
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2019 |
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http://eprints.um.edu.my/23464/ https://doi.org/10.1016/j.ica.2019.03.033 |
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