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Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)erbium(III)] dihydrate]

The 4-sulfophthalate trianion in the polymeric complex, {[Er(C 8H 3O 7S)(C 12H 8N 2)(H 2O) 2]·2H 2O} n, bridges three water/phenanthroline-coordinated Er III ions to form a three-dimensional network architecture. The metal atom is further chelated by a carboxylate group and is covalently bonded to a...

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Main Authors: Zhang, Kou-Lin, Lin, Jian-Guo, Ng, Seik Weng
Format: Article
Published: International Union of Crystallography 2012
Subjects:
Q Science (General)
QD Chemistry
Online Access:http://eprints.um.edu.my/23095/
https://doi.org/10.1107/S1600536812003467
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spelling my.um.eprints.230952019-11-22T07:33:46Z http://eprints.um.edu.my/23095/ Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)erbium(III)] dihydrate] Zhang, Kou-Lin Lin, Jian-Guo Ng, Seik Weng Q Science (General) QD Chemistry The 4-sulfophthalate trianion in the polymeric complex, {[Er(C 8H 3O 7S)(C 12H 8N 2)(H 2O) 2]·2H 2O} n, bridges three water/phenanthroline-coordinated Er III ions to form a three-dimensional network architecture. The metal atom is further chelated by a carboxylate group and is covalently bonded to a monodentate carboxylate group as well as to a monodentate sulfonate group in a distorted square antiprismatic geometry. The coordinating water molecules and the lattice water molecules, one of which is disordered over two positions [major component 65 (3)%], are hydrogen bonded to the network. International Union of Crystallography 2012 Article PeerReviewed Zhang, Kou-Lin and Lin, Jian-Guo and Ng, Seik Weng (2012) Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)erbium(III)] dihydrate]. Acta Crystallographica Section E: Structure Reports Online, 68 (2). m226-m226. ISSN 1600-5368 https://doi.org/10.1107/S1600536812003467 doi:10.1107/S1600536812003467
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
Zhang, Kou-Lin
Lin, Jian-Guo
Ng, Seik Weng
Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)erbium(III)] dihydrate]
description The 4-sulfophthalate trianion in the polymeric complex, {[Er(C 8H 3O 7S)(C 12H 8N 2)(H 2O) 2]·2H 2O} n, bridges three water/phenanthroline-coordinated Er III ions to form a three-dimensional network architecture. The metal atom is further chelated by a carboxylate group and is covalently bonded to a monodentate carboxylate group as well as to a monodentate sulfonate group in a distorted square antiprismatic geometry. The coordinating water molecules and the lattice water molecules, one of which is disordered over two positions [major component 65 (3)%], are hydrogen bonded to the network.
format Article
author Zhang, Kou-Lin
Lin, Jian-Guo
Ng, Seik Weng
author_facet Zhang, Kou-Lin
Lin, Jian-Guo
Ng, Seik Weng
author_sort Zhang, Kou-Lin
title Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)erbium(III)] dihydrate]
title_short Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)erbium(III)] dihydrate]
title_full Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)erbium(III)] dihydrate]
title_fullStr Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)erbium(III)] dihydrate]
title_full_unstemmed Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)erbium(III)] dihydrate]
title_sort poly[[diaqua(1,10-phenanthroline-κ2n,n′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4o1:o2,o2′:o4)erbium(iii)] dihydrate]
publisher International Union of Crystallography
publishDate 2012
url http://eprints.um.edu.my/23095/
https://doi.org/10.1107/S1600536812003467
_version_ 1651867398995705856
score 13.211869

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