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Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate]

The 4-sulfophthalate trianion in the polymeric title complex, {[Dy(C 8H 3O 7S)(C 12H 8N 2)(H 2O) 2]·2H 2O} n , bridges three water/phenanthroline-coordinated Dy III atoms to form a three-dimensional network architecture. The metal atom is further chelated by a carboxylate group and is covalently bon...

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Main Authors: Zhang, Kou-Lin, Lin, Jian-Guo, Ng, Seik Weng
Format: Article
Published: International Union of Crystallography 2012
Subjects:
Q Science (General)
QD Chemistry
Online Access:http://eprints.um.edu.my/23094/
https://doi.org/10.1107/S1600536812003613
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spelling my.um.eprints.230942019-11-22T07:18:59Z http://eprints.um.edu.my/23094/ Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate] Zhang, Kou-Lin Lin, Jian-Guo Ng, Seik Weng Q Science (General) QD Chemistry The 4-sulfophthalate trianion in the polymeric title complex, {[Dy(C 8H 3O 7S)(C 12H 8N 2)(H 2O) 2]·2H 2O} n , bridges three water/phenanthroline-coordinated Dy III atoms to form a three-dimensional network architecture. The metal atom is further chelated by a carboxylate group and is covalently bonded to a monodentate carboxylate group and to a monodentate sulfonate group in a distorted square-anti-prismatic geometry. The coordinating and the solvent water molecules are hydrogen bonded to the network. In the crystal, one solvent water molecule is disordered over two positions [major component = 59 (3)%]. International Union of Crystallography 2012 Article PeerReviewed Zhang, Kou-Lin and Lin, Jian-Guo and Ng, Seik Weng (2012) Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate]. Acta Crystallographica Section E: Structure Reports Online, 68 (3). m241-m241. ISSN 1600-5368 https://doi.org/10.1107/S1600536812003613 doi:10.1107/S1600536812003613
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
Zhang, Kou-Lin
Lin, Jian-Guo
Ng, Seik Weng
Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate]
description The 4-sulfophthalate trianion in the polymeric title complex, {[Dy(C 8H 3O 7S)(C 12H 8N 2)(H 2O) 2]·2H 2O} n , bridges three water/phenanthroline-coordinated Dy III atoms to form a three-dimensional network architecture. The metal atom is further chelated by a carboxylate group and is covalently bonded to a monodentate carboxylate group and to a monodentate sulfonate group in a distorted square-anti-prismatic geometry. The coordinating and the solvent water molecules are hydrogen bonded to the network. In the crystal, one solvent water molecule is disordered over two positions [major component = 59 (3)%].
format Article
author Zhang, Kou-Lin
Lin, Jian-Guo
Ng, Seik Weng
author_facet Zhang, Kou-Lin
Lin, Jian-Guo
Ng, Seik Weng
author_sort Zhang, Kou-Lin
title Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate]
title_short Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate]
title_full Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate]
title_fullStr Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate]
title_full_unstemmed Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate]
title_sort poly[[diaqua(1,10-phenanthroline-κ2n,n′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4o1:o2,o2′:o4)dysprosium(iii)] dihydrate]
publisher International Union of Crystallography
publishDate 2012
url http://eprints.um.edu.my/23094/
https://doi.org/10.1107/S1600536812003613
_version_ 1651867398841565184
score 13.164666

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