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Poly[[bis(μ-3-amino-5-carboxybenzoato-κ2N:O1)diaquazinc] dihydrate]

The ZnII atom in the title polymeric compound, {[Zn(C 8H6NO4)2(H2O) 2]·2H2O} n , lies on a center of inversion and is coordinated by two amine N atoms and two carboxyl-ate O atoms from two 3-amino-5-carb-oxy-benzoate anions along with two water mol-ecules in a distorted octa-hedral geometry. The bri...

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Main Authors: Zhang, Kou-Lin, Qiu, Ting-Ting, Ng, Seik Weng
Format: Article
Published: International Union of Crystallography 2012
Subjects:
Q Science (General)
QD Chemistry
Online Access:http://eprints.um.edu.my/23091/
https://doi.org/10.1107/S1600536812031789
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spelling my.um.eprints.230912019-11-22T06:55:23Z http://eprints.um.edu.my/23091/ Poly[[bis(μ-3-amino-5-carboxybenzoato-κ2N:O1)diaquazinc] dihydrate] Zhang, Kou-Lin Qiu, Ting-Ting Ng, Seik Weng Q Science (General) QD Chemistry The ZnII atom in the title polymeric compound, {[Zn(C 8H6NO4)2(H2O) 2]·2H2O} n , lies on a center of inversion and is coordinated by two amine N atoms and two carboxyl-ate O atoms from two 3-amino-5-carb-oxy-benzoate anions along with two water mol-ecules in a distorted octa-hedral geometry. The bridging nature of the anion generates a layer motif parallel to (100). Hydrogen bonds of the N-H⋯O and O-H⋯O types exist in the structure. One H atom of the coordinated water mol-ecule and one H atom of the solvent water mol-ecule are each disordered over two positions in a 1:1 ratio. International Union of Crystallography 2012 Article PeerReviewed Zhang, Kou-Lin and Qiu, Ting-Ting and Ng, Seik Weng (2012) Poly[[bis(μ-3-amino-5-carboxybenzoato-κ2N:O1)diaquazinc] dihydrate]. Acta Crystallographica Section E: Structure Reports Online, 68 (8). m1088-m1088. ISSN 1600-5368 https://doi.org/10.1107/S1600536812031789 doi:10.1107/S1600536812031789
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
Zhang, Kou-Lin
Qiu, Ting-Ting
Ng, Seik Weng
Poly[[bis(μ-3-amino-5-carboxybenzoato-κ2N:O1)diaquazinc] dihydrate]
description The ZnII atom in the title polymeric compound, {[Zn(C 8H6NO4)2(H2O) 2]·2H2O} n , lies on a center of inversion and is coordinated by two amine N atoms and two carboxyl-ate O atoms from two 3-amino-5-carb-oxy-benzoate anions along with two water mol-ecules in a distorted octa-hedral geometry. The bridging nature of the anion generates a layer motif parallel to (100). Hydrogen bonds of the N-H⋯O and O-H⋯O types exist in the structure. One H atom of the coordinated water mol-ecule and one H atom of the solvent water mol-ecule are each disordered over two positions in a 1:1 ratio.
format Article
author Zhang, Kou-Lin
Qiu, Ting-Ting
Ng, Seik Weng
author_facet Zhang, Kou-Lin
Qiu, Ting-Ting
Ng, Seik Weng
author_sort Zhang, Kou-Lin
title Poly[[bis(μ-3-amino-5-carboxybenzoato-κ2N:O1)diaquazinc] dihydrate]
title_short Poly[[bis(μ-3-amino-5-carboxybenzoato-κ2N:O1)diaquazinc] dihydrate]
title_full Poly[[bis(μ-3-amino-5-carboxybenzoato-κ2N:O1)diaquazinc] dihydrate]
title_fullStr Poly[[bis(μ-3-amino-5-carboxybenzoato-κ2N:O1)diaquazinc] dihydrate]
title_full_unstemmed Poly[[bis(μ-3-amino-5-carboxybenzoato-κ2N:O1)diaquazinc] dihydrate]
title_sort poly[[bis(μ-3-amino-5-carboxybenzoato-κ2n:o1)diaquazinc] dihydrate]
publisher International Union of Crystallography
publishDate 2012
url http://eprints.um.edu.my/23091/
https://doi.org/10.1107/S1600536812031789
_version_ 1651867398384386048
score 13.164666

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