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Pentaaqua(4,6-dihydroxybenzene-1,3-disulfonato-κO1)zinc pentahydrate

The Zn II atom in the title complex, [Zn(C 6H 4O 8S 2)(H 2O) 5] ·5(H 2O), is coordinated by five water mol-ecules and an O atom of a 4,6-dihy-droxy-benzene-1,3-disulfonate dianion. The coord-ination geometry is distorted octa-hedral, with the Zn-O sulfonate bond relatively long compared to the Zn-O...

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Main Authors: Zhu, Zhi-Biao, Gao, Shan, Ng, Seik Weng, Tiekink, Edward R.T.
Format: Article
Published: International Union of Crystallography 2012
Subjects:
Q Science (General)
QD Chemistry
Online Access:http://eprints.um.edu.my/23087/
https://doi.org/10.1107/S1600536812012317
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spelling my.um.eprints.230872019-11-22T04:13:01Z http://eprints.um.edu.my/23087/ Pentaaqua(4,6-dihydroxybenzene-1,3-disulfonato-κO1)zinc pentahydrate Zhu, Zhi-Biao Gao, Shan Ng, Seik Weng Tiekink, Edward R.T. Q Science (General) QD Chemistry The Zn II atom in the title complex, [Zn(C 6H 4O 8S 2)(H 2O) 5] ·5(H 2O), is coordinated by five water mol-ecules and an O atom of a 4,6-dihy-droxy-benzene-1,3-disulfonate dianion. The coord-ination geometry is distorted octa-hedral, with the Zn-O sulfonate bond relatively long compared to the Zn-O water bonds. The coordinated and lattice water mol-ecules inter-act with each other and with the hy-droxy groups and sulfonate ligand through O-H⋯O hydrogen bonds, generating a tightly held three-dimensional network. International Union of Crystallography 2012 Article PeerReviewed Zhu, Zhi-Biao and Gao, Shan and Ng, Seik Weng and Tiekink, Edward R.T. (2012) Pentaaqua(4,6-dihydroxybenzene-1,3-disulfonato-κO1)zinc pentahydrate. Acta Crystallographica Section E: Structure Reports Online, 68 (4). m492-m493. ISSN 1600-5368 https://doi.org/10.1107/S1600536812012317 doi:10.1107/S1600536812012317
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
Zhu, Zhi-Biao
Gao, Shan
Ng, Seik Weng
Tiekink, Edward R.T.
Pentaaqua(4,6-dihydroxybenzene-1,3-disulfonato-κO1)zinc pentahydrate
description The Zn II atom in the title complex, [Zn(C 6H 4O 8S 2)(H 2O) 5] ·5(H 2O), is coordinated by five water mol-ecules and an O atom of a 4,6-dihy-droxy-benzene-1,3-disulfonate dianion. The coord-ination geometry is distorted octa-hedral, with the Zn-O sulfonate bond relatively long compared to the Zn-O water bonds. The coordinated and lattice water mol-ecules inter-act with each other and with the hy-droxy groups and sulfonate ligand through O-H⋯O hydrogen bonds, generating a tightly held three-dimensional network.
format Article
author Zhu, Zhi-Biao
Gao, Shan
Ng, Seik Weng
Tiekink, Edward R.T.
author_facet Zhu, Zhi-Biao
Gao, Shan
Ng, Seik Weng
Tiekink, Edward R.T.
author_sort Zhu, Zhi-Biao
title Pentaaqua(4,6-dihydroxybenzene-1,3-disulfonato-κO1)zinc pentahydrate
title_short Pentaaqua(4,6-dihydroxybenzene-1,3-disulfonato-κO1)zinc pentahydrate
title_full Pentaaqua(4,6-dihydroxybenzene-1,3-disulfonato-κO1)zinc pentahydrate
title_fullStr Pentaaqua(4,6-dihydroxybenzene-1,3-disulfonato-κO1)zinc pentahydrate
title_full_unstemmed Pentaaqua(4,6-dihydroxybenzene-1,3-disulfonato-κO1)zinc pentahydrate
title_sort pentaaqua(4,6-dihydroxybenzene-1,3-disulfonato-κo1)zinc pentahydrate
publisher International Union of Crystallography
publishDate 2012
url http://eprints.um.edu.my/23087/
https://doi.org/10.1107/S1600536812012317
_version_ 1651867397805572096
score 13.160551

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