3-Ethenyl-1-(4-methylphenylsulfonyl)-1H-indole

Two independent but very similar molecules comprise the asymmetric unit of the title compound, C17H15NO2S. The molecules have L-shapes with the dihedral angles between the fused-ring system (r.m.s. deviations = 0.036 and 0.019 Å, respectively) and the benzene ring being almost the same, i.e. 82.98 (...

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Main Authors: Zukerman-Schpector, Julio, Wulf, Glaudeston D., Stefani, Hélio A., Vasconcelos, Stanley N.S., Ng, Seik Weng, Tiekink, Edward R.T.
Format: Article
Published: International Union of Crystallography 2012
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Online Access:http://eprints.um.edu.my/23080/
https://doi.org/10.1107/S1600536812021526
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spelling my.um.eprints.230802019-11-22T01:44:02Z http://eprints.um.edu.my/23080/ 3-Ethenyl-1-(4-methylphenylsulfonyl)-1H-indole Zukerman-Schpector, Julio Wulf, Glaudeston D. Stefani, Hélio A. Vasconcelos, Stanley N.S. Ng, Seik Weng Tiekink, Edward R.T. Q Science (General) QD Chemistry Two independent but very similar molecules comprise the asymmetric unit of the title compound, C17H15NO2S. The molecules have L-shapes with the dihedral angles between the fused-ring system (r.m.s. deviations = 0.036 and 0.019 Å, respectively) and the benzene ring being almost the same, i.e. 82.98 (12) and 84.46 (13)°, respectively. The terminal ethenyl group is almost coplanar with the ring to which it is connected [C - C - C - C torsion angles = -173.7 (4) and -171.7 (4)°, respectively]. Supramolecular arrays parallel to (1̄24) stabilized by C - H⋯O and C - H⋯π interactions feature in the crystal packing. International Union of Crystallography 2012 Article PeerReviewed Zukerman-Schpector, Julio and Wulf, Glaudeston D. and Stefani, Hélio A. and Vasconcelos, Stanley N.S. and Ng, Seik Weng and Tiekink, Edward R.T. (2012) 3-Ethenyl-1-(4-methylphenylsulfonyl)-1H-indole. Acta Crystallographica Section E: Structure Reports Online, 68 (6). o1829-o1830. ISSN 1600-5368 https://doi.org/10.1107/S1600536812021526 doi:10.1107/S1600536812021526
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
Zukerman-Schpector, Julio
Wulf, Glaudeston D.
Stefani, Hélio A.
Vasconcelos, Stanley N.S.
Ng, Seik Weng
Tiekink, Edward R.T.
3-Ethenyl-1-(4-methylphenylsulfonyl)-1H-indole
description Two independent but very similar molecules comprise the asymmetric unit of the title compound, C17H15NO2S. The molecules have L-shapes with the dihedral angles between the fused-ring system (r.m.s. deviations = 0.036 and 0.019 Å, respectively) and the benzene ring being almost the same, i.e. 82.98 (12) and 84.46 (13)°, respectively. The terminal ethenyl group is almost coplanar with the ring to which it is connected [C - C - C - C torsion angles = -173.7 (4) and -171.7 (4)°, respectively]. Supramolecular arrays parallel to (1̄24) stabilized by C - H⋯O and C - H⋯π interactions feature in the crystal packing.
format Article
author Zukerman-Schpector, Julio
Wulf, Glaudeston D.
Stefani, Hélio A.
Vasconcelos, Stanley N.S.
Ng, Seik Weng
Tiekink, Edward R.T.
author_facet Zukerman-Schpector, Julio
Wulf, Glaudeston D.
Stefani, Hélio A.
Vasconcelos, Stanley N.S.
Ng, Seik Weng
Tiekink, Edward R.T.
author_sort Zukerman-Schpector, Julio
title 3-Ethenyl-1-(4-methylphenylsulfonyl)-1H-indole
title_short 3-Ethenyl-1-(4-methylphenylsulfonyl)-1H-indole
title_full 3-Ethenyl-1-(4-methylphenylsulfonyl)-1H-indole
title_fullStr 3-Ethenyl-1-(4-methylphenylsulfonyl)-1H-indole
title_full_unstemmed 3-Ethenyl-1-(4-methylphenylsulfonyl)-1H-indole
title_sort 3-ethenyl-1-(4-methylphenylsulfonyl)-1h-indole
publisher International Union of Crystallography
publishDate 2012
url http://eprints.um.edu.my/23080/
https://doi.org/10.1107/S1600536812021526
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score 13.160551