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Poly[(μ2-4,4′-bipyridine-κ2N:N′)(μ2-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium]

In the title polymeric compound, [Cd(C9H12O 4)(C10H8N2)]n, the CdII atom is located on a twofold rotation axis and is coordinated by two 4,4′-bipyridine ligands and two 2,2-dimethylcyclopentane-1,3- dicarboxylate ions. The carboxylate ion and the N-heterocycle both function as bridges to link adjace...

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Main Authors: Zhang, Xian-Fa, Gao, Shan, Ng, Seik Weng
Format: Article
Published: International Union of Crystallography 2011
Subjects:
Q Science (General)
QD Chemistry
Online Access:http://eprints.um.edu.my/22989/
https://doi.org/10.1107/S1600536811042656
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spelling my.um.eprints.229892019-11-14T04:34:30Z http://eprints.um.edu.my/22989/ Poly[(μ2-4,4′-bipyridine-κ2N:N′)(μ2-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium] Zhang, Xian-Fa Gao, Shan Ng, Seik Weng Q Science (General) QD Chemistry In the title polymeric compound, [Cd(C9H12O 4)(C10H8N2)]n, the CdII atom is located on a twofold rotation axis and is coordinated by two 4,4′-bipyridine ligands and two 2,2-dimethylcyclopentane-1,3- dicarboxylate ions. The carboxylate ion and the N-heterocycle both function as bridges to link adjacent CdII atoms to result in the formation of a layer structure parallel to (010). The mid-point of the central C - C bond of the 4,4′-bipyridine ligand is located on an inversion center. In the crystal, the carboxylate ion is disordered over a twofold rotation axis in respect of its methyl group and the cyclo-pentane ring. © Zhang et al. 2011. International Union of Crystallography 2011 Article PeerReviewed Zhang, Xian-Fa and Gao, Shan and Ng, Seik Weng (2011) Poly[(μ2-4,4′-bipyridine-κ2N:N′)(μ2-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium]. Acta Crystallographica Section E: Structure Reports Online, 67 (11). m1593-m1593. ISSN 1600-5368 https://doi.org/10.1107/S1600536811042656 doi:10.1107/S1600536811042656
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
Zhang, Xian-Fa
Gao, Shan
Ng, Seik Weng
Poly[(μ2-4,4′-bipyridine-κ2N:N′)(μ2-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium]
description In the title polymeric compound, [Cd(C9H12O 4)(C10H8N2)]n, the CdII atom is located on a twofold rotation axis and is coordinated by two 4,4′-bipyridine ligands and two 2,2-dimethylcyclopentane-1,3- dicarboxylate ions. The carboxylate ion and the N-heterocycle both function as bridges to link adjacent CdII atoms to result in the formation of a layer structure parallel to (010). The mid-point of the central C - C bond of the 4,4′-bipyridine ligand is located on an inversion center. In the crystal, the carboxylate ion is disordered over a twofold rotation axis in respect of its methyl group and the cyclo-pentane ring. © Zhang et al. 2011.
format Article
author Zhang, Xian-Fa
Gao, Shan
Ng, Seik Weng
author_facet Zhang, Xian-Fa
Gao, Shan
Ng, Seik Weng
author_sort Zhang, Xian-Fa
title Poly[(μ2-4,4′-bipyridine-κ2N:N′)(μ2-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium]
title_short Poly[(μ2-4,4′-bipyridine-κ2N:N′)(μ2-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium]
title_full Poly[(μ2-4,4′-bipyridine-κ2N:N′)(μ2-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium]
title_fullStr Poly[(μ2-4,4′-bipyridine-κ2N:N′)(μ2-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium]
title_full_unstemmed Poly[(μ2-4,4′-bipyridine-κ2N:N′)(μ2-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ4O1,O1′:O3,O3′)cadmium]
title_sort poly[(μ2-4,4′-bipyridine-κ2n:n′)(μ2-2,2-dimethylcyclopentane-1,3-dicarboxylato-κ4o1,o1′:o3,o3′)cadmium]
publisher International Union of Crystallography
publishDate 2011
url http://eprints.um.edu.my/22989/
https://doi.org/10.1107/S1600536811042656
_version_ 1651867386126532608
score 13.18916

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