Design and the cation-templated self-assembly on the [MoOS3Cu3]+ based supramolecular polymeric clusters

• Main Authors: Zhang, Zhen-Hua, Wang, Hong-Mei, Niu, Yun-Yin, Wu, Ben-Lai, Ng, Seik Weng, Hou, Hong-Wei
• Format: Article
• Published: Elsevier 2011
• Subjects: Q Science (General); QD Chemistry
• Online Access: http://eprints.um.edu.my/22987/; https://doi.org/10.1016/j.inoche.2011.08.009

Organic cation-templated self-assembly of 4,4′-bipy (4,4′-bipy = 4,4′-bipyridine) with [NH4]2MS2O 2 (M = Mo, W) and CuX (X = I) in the presence of bppt [bppt = 1, 5-bis (pyridinium) pentane] resulted in two novel neutral heterothiometallic cluster polymers: {[Mo2O2S6Cu 6BrI(4,4′-bipy)4] (4,4′-bipy)}...