Saccharin and tert-Butyl Nitrite: Cheap and Efficient Reagents for the Synthesis of 1,2,3-Benzotriazine-4-(3H)-ones from 2-Aminobenzamides under Metal-Free Conditions
A mild and eco-friendly protocol for the synthesis of 1,2,3-benzotriazine-4-(3H)-ones is described using saccharin as a cheap and efficient catalyst and tert-butyl nitrite as a diazotization reagent for the first time. The current method has advantages such as cost effectiveness, energy efficiency,...
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my.um.eprints.216422019-07-16T08:23:47Z http://eprints.um.edu.my/21642/ Saccharin and tert-Butyl Nitrite: Cheap and Efficient Reagents for the Synthesis of 1,2,3-Benzotriazine-4-(3H)-ones from 2-Aminobenzamides under Metal-Free Conditions Khaligh, Nader Ghaffari Johan, Mohd Rafie Juan, Joon Ching QD Chemistry TA Engineering (General). Civil engineering (General) A mild and eco-friendly protocol for the synthesis of 1,2,3-benzotriazine-4-(3H)-ones is described using saccharin as a cheap and efficient catalyst and tert-butyl nitrite as a diazotization reagent for the first time. The current method has advantages such as cost effectiveness, energy efficiency, and simple experimental procedure, good yield of the desired product, and metal-free and environmentally benign conditions. CSIRO Publishing 2018 Article PeerReviewed Khaligh, Nader Ghaffari and Johan, Mohd Rafie and Juan, Joon Ching (2018) Saccharin and tert-Butyl Nitrite: Cheap and Efficient Reagents for the Synthesis of 1,2,3-Benzotriazine-4-(3H)-ones from 2-Aminobenzamides under Metal-Free Conditions. Australian Journal of Chemistry, 71 (3). pp. 186-189. ISSN 0004-9425 https://doi.org/10.1071/CH17590 doi:10.1071/CH17590 |
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QD Chemistry TA Engineering (General). Civil engineering (General) Khaligh, Nader Ghaffari Johan, Mohd Rafie Juan, Joon Ching Saccharin and tert-Butyl Nitrite: Cheap and Efficient Reagents for the Synthesis of 1,2,3-Benzotriazine-4-(3H)-ones from 2-Aminobenzamides under Metal-Free Conditions |
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A mild and eco-friendly protocol for the synthesis of 1,2,3-benzotriazine-4-(3H)-ones is described using saccharin as a cheap and efficient catalyst and tert-butyl nitrite as a diazotization reagent for the first time. The current method has advantages such as cost effectiveness, energy efficiency, and simple experimental procedure, good yield of the desired product, and metal-free and environmentally benign conditions. |
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Article |
author |
Khaligh, Nader Ghaffari Johan, Mohd Rafie Juan, Joon Ching |
author_facet |
Khaligh, Nader Ghaffari Johan, Mohd Rafie Juan, Joon Ching |
author_sort |
Khaligh, Nader Ghaffari |
title |
Saccharin and tert-Butyl Nitrite: Cheap and Efficient Reagents for the Synthesis of 1,2,3-Benzotriazine-4-(3H)-ones from 2-Aminobenzamides under Metal-Free Conditions |
title_short |
Saccharin and tert-Butyl Nitrite: Cheap and Efficient Reagents for the Synthesis of 1,2,3-Benzotriazine-4-(3H)-ones from 2-Aminobenzamides under Metal-Free Conditions |
title_full |
Saccharin and tert-Butyl Nitrite: Cheap and Efficient Reagents for the Synthesis of 1,2,3-Benzotriazine-4-(3H)-ones from 2-Aminobenzamides under Metal-Free Conditions |
title_fullStr |
Saccharin and tert-Butyl Nitrite: Cheap and Efficient Reagents for the Synthesis of 1,2,3-Benzotriazine-4-(3H)-ones from 2-Aminobenzamides under Metal-Free Conditions |
title_full_unstemmed |
Saccharin and tert-Butyl Nitrite: Cheap and Efficient Reagents for the Synthesis of 1,2,3-Benzotriazine-4-(3H)-ones from 2-Aminobenzamides under Metal-Free Conditions |
title_sort |
saccharin and tert-butyl nitrite: cheap and efficient reagents for the synthesis of 1,2,3-benzotriazine-4-(3h)-ones from 2-aminobenzamides under metal-free conditions |
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CSIRO Publishing |
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2018 |
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http://eprints.um.edu.my/21642/ https://doi.org/10.1071/CH17590 |
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1643691618329427968 |
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13.18916 |