CdSe/TiO2 nanotubes for enhanced photoelectrochemical activity under solar illumination: Influence of soaking time in CdSe bath solution

In the present study, nanotubular structure of cadmium selenide/titanium dioxide (CdSe/TiO2) was successfully prepared via chemical bath deposition (CBD) chemosynthesis method to improve photoelectrochemical activity under solar illumination. The results revealed that optimum CdSe dopants incorporat...

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Bibliographic Details
Main Authors: Lai, Chin Wei, Lau, Kung Shiuh, Chou, Pui May
Format: Article
Published: Elsevier 2019
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Online Access:http://eprints.um.edu.my/20043/
https://doi.org/10.1016/j.cplett.2018.10.054
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Summary:In the present study, nanotubular structure of cadmium selenide/titanium dioxide (CdSe/TiO2) was successfully prepared via chemical bath deposition (CBD) chemosynthesis method to improve photoelectrochemical activity under solar illumination. The results revealed that optimum CdSe dopants incorporated into TiO2 nanotubes played a crucial role in determining the photoelectrode performance in water splitting. It was found that synthesized CdSe/TiO2 nanotubes soaked at 30 min of CdSe precursor showed a maximum photocurrent density of 0.0016 A/cm2 with improvement of about 10% than that of pure TiO2 nanotubes under solar illumination. The presence of optimum contents of CdSe dopants incorporated into TiO2 nanotubes could act as efficient mediators for trapping photo-induced electrons and reduce the recombination losses of charge carriers significantly.