The importance of Au⋯π(aryl) interactions in the formation of spherical aggregates in binuclear phosphane gold(i) complexes of a bipodal thiocarbamate dianion: a combined crystallographic and computational study, and anti-microbial activity
Binuclear phosphanegold(i) complexes of a bipodal thiocarbamate dianion, (R3PAu)2L, R = Et (1), Ph (2) and Cy (3), where LH2 is {1,4-[MeOC(S)N(H)]2C6H4}, have been synthesised, and characterised spectroscopically (NMR and IR) and by X-ray crystallography. The gold atoms are linearly coordinated with...
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Main Authors: | , , , , , , , , , , , , |
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Format: | Article |
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Royal Society of Chemistry
2015
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Online Access: | http://eprints.um.edu.my/19375/ http://dx.doi.org/10.1039/C5RA05604G |
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