[N′-(4-Decyloxy-2-oxidobenzylidene)-3-hydroxy-2-naphthohydrazidato-κ3N,O,O′]dimethyltin(IV): crystal structure and Hirshfeld surface analysis

• Main Authors: Rosely, S.N.M., Hussen, R.S.D., Lee, S.M., Halcovitch, N.R., Jotani, M.M., Tiekink, E.R.T.
• Format: Article
• Language: English
• Published: International Union of Crystallography 2017
• Subjects: QD Chemistry
• Online Access: http://eprints.um.edu.my/19039/1/Di-methyl-tin%28IV%29-Crystal_structure_and_Hirshfeld_surface_analysis.pdf; http://eprints.um.edu.my/19039/; http://dx.doi.org/10.1107/S2056989017002365

The title diorganotin compound, [Sn(CH3)2(C28H32N2O4)], features a distorted SnC2NO2 coordination geometry almost inter-mediate between ideal trigonal-bipyramidal and square-pyramidal. The dianionic Schiff base ligand coordinates in a tridentate fashion via two alkoxide O and hydrazinyl N atoms; an...