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Supramolecular architectures sustained by arene-C-H⋯π(quasi-chelate ring) interactions in the crystal structures of copper(I) complexes

A review of the crystallographic literature is presented whereby structures featuring a quasi-six-membered chelate ring of the type {CuCl⋯HNCS} were evaluated for the presence of intermolecular C-H⋯π(quasi-chelate) interactions. These are shown to stabilise crystal structures leading to zero-, one-,...

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Main Authors: Zukerman-Schpector, J., Yeo, C.I., Tiekink, E.R.T.
Format: Article
Published: De Gruyter 2016
Subjects:
Q Science (General)
QD Chemistry
Online Access:http://eprints.um.edu.my/18651/
https://doi.org/10.1515/zkri-2015-1868
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spelling my.um.eprints.186512020-05-20T00:28:17Z http://eprints.um.edu.my/18651/ Supramolecular architectures sustained by arene-C-H⋯π(quasi-chelate ring) interactions in the crystal structures of copper(I) complexes Zukerman-Schpector, J. Yeo, C.I. Tiekink, E.R.T. Q Science (General) QD Chemistry A review of the crystallographic literature is presented whereby structures featuring a quasi-six-membered chelate ring of the type {CuCl⋯HNCS} were evaluated for the presence of intermolecular C-H⋯π(quasi-chelate) interactions. These are shown to stabilise crystal structures leading to zero-, one-, two- and even three-dimensional architectures. Details of these interactions are described and a comparison to analogous interactions formed intramolecularly has been made. The C-H⋯π(quasi-chelate) interactions in these structures occur in one-third of structures where such contacts can potentially form. De Gruyter 2016 Article PeerReviewed Zukerman-Schpector, J. and Yeo, C.I. and Tiekink, E.R.T. (2016) Supramolecular architectures sustained by arene-C-H⋯π(quasi-chelate ring) interactions in the crystal structures of copper(I) complexes. Zeitschrift fur Kristallographie Crystalline Materials, 231 (1). pp. 55-64. ISSN 2194-4946 https://doi.org/10.1515/zkri-2015-1868 doi:10.1515/zkri-2015-1868
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
Zukerman-Schpector, J.
Yeo, C.I.
Tiekink, E.R.T.
Supramolecular architectures sustained by arene-C-H⋯π(quasi-chelate ring) interactions in the crystal structures of copper(I) complexes
description A review of the crystallographic literature is presented whereby structures featuring a quasi-six-membered chelate ring of the type {CuCl⋯HNCS} were evaluated for the presence of intermolecular C-H⋯π(quasi-chelate) interactions. These are shown to stabilise crystal structures leading to zero-, one-, two- and even three-dimensional architectures. Details of these interactions are described and a comparison to analogous interactions formed intramolecularly has been made. The C-H⋯π(quasi-chelate) interactions in these structures occur in one-third of structures where such contacts can potentially form.
format Article
author Zukerman-Schpector, J.
Yeo, C.I.
Tiekink, E.R.T.
author_facet Zukerman-Schpector, J.
Yeo, C.I.
Tiekink, E.R.T.
author_sort Zukerman-Schpector, J.
title Supramolecular architectures sustained by arene-C-H⋯π(quasi-chelate ring) interactions in the crystal structures of copper(I) complexes
title_short Supramolecular architectures sustained by arene-C-H⋯π(quasi-chelate ring) interactions in the crystal structures of copper(I) complexes
title_full Supramolecular architectures sustained by arene-C-H⋯π(quasi-chelate ring) interactions in the crystal structures of copper(I) complexes
title_fullStr Supramolecular architectures sustained by arene-C-H⋯π(quasi-chelate ring) interactions in the crystal structures of copper(I) complexes
title_full_unstemmed Supramolecular architectures sustained by arene-C-H⋯π(quasi-chelate ring) interactions in the crystal structures of copper(I) complexes
title_sort supramolecular architectures sustained by arene-c-h⋯π(quasi-chelate ring) interactions in the crystal structures of copper(i) complexes
publisher De Gruyter
publishDate 2016
url http://eprints.um.edu.my/18651/
https://doi.org/10.1515/zkri-2015-1868
_version_ 1669007986142478336
score 13.188404

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