Triethylene glycol based deep eutectic solvents and their physical properties

• Main Authors: Hayyan, M., Aissaoui, T., Hashim, M.A., AlSaadi, M.A., Hayyan, A.
• Format: Article
• Language: English
• Published: Elsevier 2015
• Subjects: T Technology (General); TA Engineering (General). Civil engineering (General); TP Chemical technology
• Online Access: http://eprints.um.edu.my/15681/1/Triethylene_glycol_based_deep_eutectic_solvents_and_their_physical_properties.pdf; http://eprints.um.edu.my/15681/; https://doi.org/10.1016/j.jtice.2015.03.001

Deep eutectic solvents (DESs) have been recently emerged as new ionic liquids (ILs) analogues. The low vapor pressure, inflammability, biodegradability and positive effect on the environment make DESs more favorable as neoteric solvents. In this study, triethylene glycol (TEG) was selected as a hydrogen bond donor (HBD) to form DESs with five types of phosphonium and ammonium salts, namely methyltriphenylphosphonium bromide (MTPB), benzyltriphenylphosphonium chloride (BTPC), allyltriphenylphosphonium bromide (ATPB), choline chloride (2-hydroxyethyl-trimethylammonium) (ChCl) and N,N-diethylenethanolammonium chloride (DAC). The physical properties of the synthesized DESs were measured such as freezing point, viscosity, electrical conductivity, Walden rule, density, pH and water content. In addition, the Fourier transform infrared spectroscopy (FTIR) was employed to study the functional groups. The experiments were conducted at different temperatures, i.e. 25-80 degrees C. It was found that DESs have suitable properties to be used in industrial processes such as separation, extraction, biochemical, petroleum and gas technology. (C) 2015 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.