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[N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dimethyltin(IV)

The Sn-IV atom in the title compound, [Sn(CH3)(2)(C18H11BrN2O3)], shows a distorted cis-C2NO2Sn trigonal-bipyramidal coordination geometry, with an axial O-Sn-O angle of 155.27 (9)degrees. The presence of an intramolecular O-H center dot center dot center dot N hydrogen bond between the amido N atom...

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Main Authors: Lee, S.M., Ali, H.M., Lo, K.M.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
QC Physics
Online Access:http://eprints.um.edu.my/15202/
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spelling my.um.eprints.152022019-01-29T08:58:00Z http://eprints.um.edu.my/15202/ [N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dimethyltin(IV) Lee, S.M. Ali, H.M. Lo, K.M. QC Physics The Sn-IV atom in the title compound, [Sn(CH3)(2)(C18H11BrN2O3)], shows a distorted cis-C2NO2Sn trigonal-bipyramidal coordination geometry, with an axial O-Sn-O angle of 155.27 (9)degrees. The presence of an intramolecular O-H center dot center dot center dot N hydrogen bond between the amido N atom and hydroxy H atom in the Schiff base ligand helps to stabilize the overall molecular structure. International Union of Crystallography 2010 Article PeerReviewed Lee, S.M. and Ali, H.M. and Lo, K.M. (2010) [N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dimethyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (2). M161-U706. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QC Physics
spellingShingle QC Physics
Lee, S.M.
Ali, H.M.
Lo, K.M.
[N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dimethyltin(IV)
description The Sn-IV atom in the title compound, [Sn(CH3)(2)(C18H11BrN2O3)], shows a distorted cis-C2NO2Sn trigonal-bipyramidal coordination geometry, with an axial O-Sn-O angle of 155.27 (9)degrees. The presence of an intramolecular O-H center dot center dot center dot N hydrogen bond between the amido N atom and hydroxy H atom in the Schiff base ligand helps to stabilize the overall molecular structure.
format Article
author Lee, S.M.
Ali, H.M.
Lo, K.M.
author_facet Lee, S.M.
Ali, H.M.
Lo, K.M.
author_sort Lee, S.M.
title [N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dimethyltin(IV)
title_short [N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dimethyltin(IV)
title_full [N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dimethyltin(IV)
title_fullStr [N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dimethyltin(IV)
title_full_unstemmed [N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dimethyltin(IV)
title_sort [n `-(5-bromo-2-oxidobenzylidene-kappa o)-3-hydroxy-2-naphthohydrazidato-kappa n-2 `,o]dimethyltin(iv)
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/15202/
_version_ 1643690000760438784
score 13.19449

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