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(2,2 `-Bipyridine-kappa N-2,N `)bis(N-ethyl-N-methyldithiocarbamato-kappa S-2,S `)zinc(II)

The complete molecule of the title compound, [Zn(C4H8NS2)(2)(C10H8N2)], is generated by crystallographic twofold symmetry, with the Zn atom lying on the rotation axis; the axis also bisects the central C-C bond of the 2,2'-bipyridine molecule. The metal atom is chelated by two S,S'-bidenta...

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Main Authors: Ghafar, N.A.A., Baba, I., Yamin, B.M., Ng, S.W.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
QC Physics
Online Access:http://eprints.um.edu.my/15201/
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spelling my.um.eprints.152012019-01-31T04:11:08Z http://eprints.um.edu.my/15201/ (2,2 `-Bipyridine-kappa N-2,N `)bis(N-ethyl-N-methyldithiocarbamato-kappa S-2,S `)zinc(II) Ghafar, N.A.A. Baba, I. Yamin, B.M. Ng, S.W. QC Physics The complete molecule of the title compound, [Zn(C4H8NS2)(2)(C10H8N2)], is generated by crystallographic twofold symmetry, with the Zn atom lying on the rotation axis; the axis also bisects the central C-C bond of the 2,2'-bipyridine molecule. The metal atom is chelated by two S,S'-bidentate dithiocarbamate anions and the N,N'-bidentate heterocycle, resulting in a distorted cis-ZnN2S4 octahedral geometry. The methyl and ethyl groups of the anion are statistically disordered. International Union of Crystallography 2010 Article PeerReviewed Ghafar, N.A.A. and Baba, I. and Yamin, B.M. and Ng, S.W. (2010) (2,2 `-Bipyridine-kappa N-2,N `)bis(N-ethyl-N-methyldithiocarbamato-kappa S-2,S `)zinc(II). Acta Crystallographica Section E: Structure Reports Online, 66 (2). M208-U1129. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QC Physics
spellingShingle QC Physics
Ghafar, N.A.A.
Baba, I.
Yamin, B.M.
Ng, S.W.
(2,2 `-Bipyridine-kappa N-2,N `)bis(N-ethyl-N-methyldithiocarbamato-kappa S-2,S `)zinc(II)
description The complete molecule of the title compound, [Zn(C4H8NS2)(2)(C10H8N2)], is generated by crystallographic twofold symmetry, with the Zn atom lying on the rotation axis; the axis also bisects the central C-C bond of the 2,2'-bipyridine molecule. The metal atom is chelated by two S,S'-bidentate dithiocarbamate anions and the N,N'-bidentate heterocycle, resulting in a distorted cis-ZnN2S4 octahedral geometry. The methyl and ethyl groups of the anion are statistically disordered.
format Article
author Ghafar, N.A.A.
Baba, I.
Yamin, B.M.
Ng, S.W.
author_facet Ghafar, N.A.A.
Baba, I.
Yamin, B.M.
Ng, S.W.
author_sort Ghafar, N.A.A.
title (2,2 `-Bipyridine-kappa N-2,N `)bis(N-ethyl-N-methyldithiocarbamato-kappa S-2,S `)zinc(II)
title_short (2,2 `-Bipyridine-kappa N-2,N `)bis(N-ethyl-N-methyldithiocarbamato-kappa S-2,S `)zinc(II)
title_full (2,2 `-Bipyridine-kappa N-2,N `)bis(N-ethyl-N-methyldithiocarbamato-kappa S-2,S `)zinc(II)
title_fullStr (2,2 `-Bipyridine-kappa N-2,N `)bis(N-ethyl-N-methyldithiocarbamato-kappa S-2,S `)zinc(II)
title_full_unstemmed (2,2 `-Bipyridine-kappa N-2,N `)bis(N-ethyl-N-methyldithiocarbamato-kappa S-2,S `)zinc(II)
title_sort (2,2 `-bipyridine-kappa n-2,n `)bis(n-ethyl-n-methyldithiocarbamato-kappa s-2,s `)zinc(ii)
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/15201/
_version_ 1643690000475226112
score 13.209306

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