7-Chloro-4-[(E)-2-(4-methoxybenzylidene)hydrazin-1-yl]quinoline monohydrate
The organic molecule in the title hydrate, C17H14ClN3O center dot H2O, has a small but significant twist from planarity, as seen in the dihedral angle of 12.10 (17)degrees between the quinoline and benzene rings. The conformation about the C=N bond is E. Chains along the b axis are formed in the cry...
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my.um.eprints.150282019-01-31T04:05:04Z http://eprints.um.edu.my/15028/ 7-Chloro-4-[(E)-2-(4-methoxybenzylidene)hydrazin-1-yl]quinoline monohydrate Ferreira, M.L. de Souza, M.V.N. Howie, R.A. Tiekink, E.R.T. Wardell, J.L. Wardell, S.M.S.V. Q Science (General) The organic molecule in the title hydrate, C17H14ClN3O center dot H2O, has a small but significant twist from planarity, as seen in the dihedral angle of 12.10 (17)degrees between the quinoline and benzene rings. The conformation about the C=N bond is E. Chains along the b axis are formed in the crystal structure aided by water-quinoline O-H center dot center dot center dot N (x 2) and hydrazone-water N-H center dot center dot center dot O hydrogen bonds. Layers of these chains stack along the a axis via C-H center dot center dot center dot pi and pi-pi interactions [ring centroid-ring centroid distance = 3.674 (2) angstrom]. C-H center dot center dot center dot O interactions are also present. International Union of Crystallography 2010 Article PeerReviewed Ferreira, M.L. and de Souza, M.V.N. and Howie, R.A. and Tiekink, E.R.T. and Wardell, J.L. and Wardell, S.M.S.V. (2010) 7-Chloro-4-[(E)-2-(4-methoxybenzylidene)hydrazin-1-yl]quinoline monohydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (3). O696-U5690. ISSN 1600-5368 |
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Q Science (General) Ferreira, M.L. de Souza, M.V.N. Howie, R.A. Tiekink, E.R.T. Wardell, J.L. Wardell, S.M.S.V. 7-Chloro-4-[(E)-2-(4-methoxybenzylidene)hydrazin-1-yl]quinoline monohydrate |
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The organic molecule in the title hydrate, C17H14ClN3O center dot H2O, has a small but significant twist from planarity, as seen in the dihedral angle of 12.10 (17)degrees between the quinoline and benzene rings. The conformation about the C=N bond is E. Chains along the b axis are formed in the crystal structure aided by water-quinoline O-H center dot center dot center dot N (x 2) and hydrazone-water N-H center dot center dot center dot O hydrogen bonds. Layers of these chains stack along the a axis via C-H center dot center dot center dot pi and pi-pi interactions [ring centroid-ring centroid distance = 3.674 (2) angstrom]. C-H center dot center dot center dot O interactions are also present. |
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Article |
author |
Ferreira, M.L. de Souza, M.V.N. Howie, R.A. Tiekink, E.R.T. Wardell, J.L. Wardell, S.M.S.V. |
author_facet |
Ferreira, M.L. de Souza, M.V.N. Howie, R.A. Tiekink, E.R.T. Wardell, J.L. Wardell, S.M.S.V. |
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Ferreira, M.L. |
title |
7-Chloro-4-[(E)-2-(4-methoxybenzylidene)hydrazin-1-yl]quinoline monohydrate |
title_short |
7-Chloro-4-[(E)-2-(4-methoxybenzylidene)hydrazin-1-yl]quinoline monohydrate |
title_full |
7-Chloro-4-[(E)-2-(4-methoxybenzylidene)hydrazin-1-yl]quinoline monohydrate |
title_fullStr |
7-Chloro-4-[(E)-2-(4-methoxybenzylidene)hydrazin-1-yl]quinoline monohydrate |
title_full_unstemmed |
7-Chloro-4-[(E)-2-(4-methoxybenzylidene)hydrazin-1-yl]quinoline monohydrate |
title_sort |
7-chloro-4-[(e)-2-(4-methoxybenzylidene)hydrazin-1-yl]quinoline monohydrate |
publisher |
International Union of Crystallography |
publishDate |
2010 |
url |
http://eprints.um.edu.my/15028/ |
_version_ |
1643689960550694912 |
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13.160551 |