Bis(3,5-dinitrobenzoato-kappa O-1)tetramethanolcobalt(II)
The Co-II atom (site symmetry 1) in the title complex, [Co(C7H3N2O6)(2)(CH3OH)(4)], exists within an octahedral O-6 donor set defined by two O-monodentate 3,5-dinitrobenzoate anions and four methanol O atoms. An intramolecular O-m-H center dot center dot center dot Oc (m = methanol and c = carbonyl)...
Saved in:
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Published: |
International Union of Crystallography
2010
|
| Subjects: | |
| Online Access: | http://eprints.um.edu.my/14773/ |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Summary: | The Co-II atom (site symmetry 1) in the title complex, [Co(C7H3N2O6)(2)(CH3OH)(4)], exists within an octahedral O-6 donor set defined by two O-monodentate 3,5-dinitrobenzoate anions and four methanol O atoms. An intramolecular O-m-H center dot center dot center dot Oc (m = methanol and c = carbonyl) hydrogen bond leads to the formation of an S(6) ring. In the crystal, centrosymmetrically related molecules associate via further O-m-H center dot center dot center dot Oc hydrogen bonds, leading to linear supramolecular chains propagating along the a-axis direction. |
|---|