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Bis(acetato-kappa O-2,O `)diphenyl(pyridine-kappa N)tin(IV)

The asymmetric unit of the title compound, [Sn(C6H5)(2)-(C2H3O2)(2)(C5H5N)], contains two crystallography independent molecules. In both molecules, the Sn-IV atom is sevencoordinated in a distorted pentagonal-bipyramidal geometry with the two phenyl groups in axial positions. The two molecules diffe...

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Main Authors: Khaledi, H., Ali, H.M., Abdulla, M.A.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
QC Physics
Online Access:http://eprints.um.edu.my/14766/
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spelling my.um.eprints.147662019-01-29T09:10:48Z http://eprints.um.edu.my/14766/ Bis(acetato-kappa O-2,O `)diphenyl(pyridine-kappa N)tin(IV) Khaledi, H. Ali, H.M. Abdulla, M.A. QC Physics The asymmetric unit of the title compound, [Sn(C6H5)(2)-(C2H3O2)(2)(C5H5N)], contains two crystallography independent molecules. In both molecules, the Sn-IV atom is sevencoordinated in a distorted pentagonal-bipyramidal geometry with the two phenyl groups in axial positions. The two molecules differ mainly in the torsion of the phenyl and pyridine rings. The dihredral angles between the phenyl rings are 89.54 (15)and 60.11 (14)degrees in the two molecules while the dihedral angles between the pyridine rings and the acetate groups are 12.6 (2)and 41.77 (13)degrees in the two molecules. International Union of Crystallography 2010 Article PeerReviewed Khaledi, H. and Ali, H.M. and Abdulla, M.A. (2010) Bis(acetato-kappa O-2,O `)diphenyl(pyridine-kappa N)tin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (4). M351-U184. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QC Physics
spellingShingle QC Physics
Khaledi, H.
Ali, H.M.
Abdulla, M.A.
Bis(acetato-kappa O-2,O `)diphenyl(pyridine-kappa N)tin(IV)
description The asymmetric unit of the title compound, [Sn(C6H5)(2)-(C2H3O2)(2)(C5H5N)], contains two crystallography independent molecules. In both molecules, the Sn-IV atom is sevencoordinated in a distorted pentagonal-bipyramidal geometry with the two phenyl groups in axial positions. The two molecules differ mainly in the torsion of the phenyl and pyridine rings. The dihredral angles between the phenyl rings are 89.54 (15)and 60.11 (14)degrees in the two molecules while the dihedral angles between the pyridine rings and the acetate groups are 12.6 (2)and 41.77 (13)degrees in the two molecules.
format Article
author Khaledi, H.
Ali, H.M.
Abdulla, M.A.
author_facet Khaledi, H.
Ali, H.M.
Abdulla, M.A.
author_sort Khaledi, H.
title Bis(acetato-kappa O-2,O `)diphenyl(pyridine-kappa N)tin(IV)
title_short Bis(acetato-kappa O-2,O `)diphenyl(pyridine-kappa N)tin(IV)
title_full Bis(acetato-kappa O-2,O `)diphenyl(pyridine-kappa N)tin(IV)
title_fullStr Bis(acetato-kappa O-2,O `)diphenyl(pyridine-kappa N)tin(IV)
title_full_unstemmed Bis(acetato-kappa O-2,O `)diphenyl(pyridine-kappa N)tin(IV)
title_sort bis(acetato-kappa o-2,o `)diphenyl(pyridine-kappa n)tin(iv)
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/14766/
_version_ 1643689894961217536
score 13.19449

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