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Di-mu-acetato-1:2 kappa O-2:O `;2:3 kappa O-3:O,O `-bis(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)-1 kappa N-4,3 kappa N-4-bis(perchlorato-2 kappa O-2,O `)-2-sodium-1,3-dizinc perchlorate

In the title salt, [NaZn2(CH3COO)(2)(ClO4)(2)(C16H36N4)(2)]ClO4, the macrocyclic ligand binds to the Zn2+ cations through their four amino N atoms; the Zn2+ cations are also each covalently bonded to an acetate ion. For one zinc atom, the acetate group is monodentate, and the geometry is a distorted...

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Main Authors: Ou, Guang-Chuan, Ng, S.W.
Format: Article
Published: International Union of Crystallography 2011
Subjects:
QC Physics
Online Access:http://eprints.um.edu.my/14664/
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spelling my.um.eprints.146642019-01-31T05:11:14Z http://eprints.um.edu.my/14664/ Di-mu-acetato-1:2 kappa O-2:O `;2:3 kappa O-3:O,O `-bis(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)-1 kappa N-4,3 kappa N-4-bis(perchlorato-2 kappa O-2,O `)-2-sodium-1,3-dizinc perchlorate Ou, Guang-Chuan Ng, S.W. QC Physics In the title salt, [NaZn2(CH3COO)(2)(ClO4)(2)(C16H36N4)(2)]ClO4, the macrocyclic ligand binds to the Zn2+ cations through their four amino N atoms; the Zn2+ cations are also each covalently bonded to an acetate ion. For one zinc atom, the acetate group is monodentate, and the geometry is a distorted ZnN4O trigonal bipyramid; for the other, the acetate group is anisobidentate and the geometry is a distorted ZnN4O2 octahedron. The two macrocycle-zinc acetate units are bridged through a diperchloratosodium unit. In the crystal, the complex cations and uncoordinated perchlorate anions are linked by N-H center dot center dot center dot O hydrogen bonds. International Union of Crystallography 2011 Article PeerReviewed Ou, Guang-Chuan and Ng, S.W. (2011) Di-mu-acetato-1:2 kappa O-2:O `;2:3 kappa O-3:O,O `-bis(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)-1 kappa N-4,3 kappa N-4-bis(perchlorato-2 kappa O-2,O `)-2-sodium-1,3-dizinc perchlorate. Acta Crystallographica Section E: Structure Reports Online, 67 (12). O1664-U1342. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QC Physics
spellingShingle QC Physics
Ou, Guang-Chuan
Ng, S.W.
Di-mu-acetato-1:2 kappa O-2:O `;2:3 kappa O-3:O,O `-bis(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)-1 kappa N-4,3 kappa N-4-bis(perchlorato-2 kappa O-2,O `)-2-sodium-1,3-dizinc perchlorate
description In the title salt, [NaZn2(CH3COO)(2)(ClO4)(2)(C16H36N4)(2)]ClO4, the macrocyclic ligand binds to the Zn2+ cations through their four amino N atoms; the Zn2+ cations are also each covalently bonded to an acetate ion. For one zinc atom, the acetate group is monodentate, and the geometry is a distorted ZnN4O trigonal bipyramid; for the other, the acetate group is anisobidentate and the geometry is a distorted ZnN4O2 octahedron. The two macrocycle-zinc acetate units are bridged through a diperchloratosodium unit. In the crystal, the complex cations and uncoordinated perchlorate anions are linked by N-H center dot center dot center dot O hydrogen bonds.
format Article
author Ou, Guang-Chuan
Ng, S.W.
author_facet Ou, Guang-Chuan
Ng, S.W.
author_sort Ou, Guang-Chuan
title Di-mu-acetato-1:2 kappa O-2:O `;2:3 kappa O-3:O,O `-bis(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)-1 kappa N-4,3 kappa N-4-bis(perchlorato-2 kappa O-2,O `)-2-sodium-1,3-dizinc perchlorate
title_short Di-mu-acetato-1:2 kappa O-2:O `;2:3 kappa O-3:O,O `-bis(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)-1 kappa N-4,3 kappa N-4-bis(perchlorato-2 kappa O-2,O `)-2-sodium-1,3-dizinc perchlorate
title_full Di-mu-acetato-1:2 kappa O-2:O `;2:3 kappa O-3:O,O `-bis(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)-1 kappa N-4,3 kappa N-4-bis(perchlorato-2 kappa O-2,O `)-2-sodium-1,3-dizinc perchlorate
title_fullStr Di-mu-acetato-1:2 kappa O-2:O `;2:3 kappa O-3:O,O `-bis(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)-1 kappa N-4,3 kappa N-4-bis(perchlorato-2 kappa O-2,O `)-2-sodium-1,3-dizinc perchlorate
title_full_unstemmed Di-mu-acetato-1:2 kappa O-2:O `;2:3 kappa O-3:O,O `-bis(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)-1 kappa N-4,3 kappa N-4-bis(perchlorato-2 kappa O-2,O `)-2-sodium-1,3-dizinc perchlorate
title_sort di-mu-acetato-1:2 kappa o-2:o `;2:3 kappa o-3:o,o `-bis(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)-1 kappa n-4,3 kappa n-4-bis(perchlorato-2 kappa o-2,o `)-2-sodium-1,3-dizinc perchlorate
publisher International Union of Crystallography
publishDate 2011
url http://eprints.um.edu.my/14664/
_version_ 1643689872016277504
score 13.211869

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