Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-kappa N)ethylidene]thiosemicarbazidato-kappa N-2(1),S}methyltin(IV)
The monodeprotonated Schiff base ligand in the title compound, [Sn(CH3)(C14H19N4S)Cl-2], N,N',S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are positioned...
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my.um.eprints.142752019-01-31T04:52:04Z http://eprints.um.edu.my/14275/ Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-kappa N)ethylidene]thiosemicarbazidato-kappa N-2(1),S}methyltin(IV) Salam, M.A. Abu Affan, M. Shamsuddin, M. Ng, S.W. Q Science (General) The monodeprotonated Schiff base ligand in the title compound, [Sn(CH3)(C14H19N4S)Cl-2], N,N',S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent molecule, the hydrogen bond giving rise to a helical chain extending parallel to [100]. International Union of Crystallography 2010 Article PeerReviewed Salam, M.A. and Abu Affan, M. and Shamsuddin, M. and Ng, S.W. (2010) Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-kappa N)ethylidene]thiosemicarbazidato-kappa N-2(1),S}methyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (5). M570-U939. ISSN 1600-5368 |
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Q Science (General) Salam, M.A. Abu Affan, M. Shamsuddin, M. Ng, S.W. Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-kappa N)ethylidene]thiosemicarbazidato-kappa N-2(1),S}methyltin(IV) |
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The monodeprotonated Schiff base ligand in the title compound, [Sn(CH3)(C14H19N4S)Cl-2], N,N',S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent molecule, the hydrogen bond giving rise to a helical chain extending parallel to [100]. |
format |
Article |
author |
Salam, M.A. Abu Affan, M. Shamsuddin, M. Ng, S.W. |
author_facet |
Salam, M.A. Abu Affan, M. Shamsuddin, M. Ng, S.W. |
author_sort |
Salam, M.A. |
title |
Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-kappa N)ethylidene]thiosemicarbazidato-kappa N-2(1),S}methyltin(IV) |
title_short |
Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-kappa N)ethylidene]thiosemicarbazidato-kappa N-2(1),S}methyltin(IV) |
title_full |
Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-kappa N)ethylidene]thiosemicarbazidato-kappa N-2(1),S}methyltin(IV) |
title_fullStr |
Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-kappa N)ethylidene]thiosemicarbazidato-kappa N-2(1),S}methyltin(IV) |
title_full_unstemmed |
Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-kappa N)ethylidene]thiosemicarbazidato-kappa N-2(1),S}methyltin(IV) |
title_sort |
dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-kappa n)ethylidene]thiosemicarbazidato-kappa n-2(1),s}methyltin(iv) |
publisher |
International Union of Crystallography |
publishDate |
2010 |
url |
http://eprints.um.edu.my/14275/ |
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1643689768969568256 |
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13.18916 |