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Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-kappa N)ethylidene]thiosemicarbazidato-kappa N-2(1),S}methyltin(IV)

The monodeprotonated Schiff base ligand in the title compound, [Sn(CH3)(C14H19N4S)Cl-2], N,N',S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are positioned...

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Main Authors: Salam, M.A., Abu Affan, M., Shamsuddin, M., Ng, S.W.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/14275/
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spelling my.um.eprints.142752019-01-31T04:52:04Z http://eprints.um.edu.my/14275/ Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-kappa N)ethylidene]thiosemicarbazidato-kappa N-2(1),S}methyltin(IV) Salam, M.A. Abu Affan, M. Shamsuddin, M. Ng, S.W. Q Science (General) The monodeprotonated Schiff base ligand in the title compound, [Sn(CH3)(C14H19N4S)Cl-2], N,N',S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent molecule, the hydrogen bond giving rise to a helical chain extending parallel to [100]. International Union of Crystallography 2010 Article PeerReviewed Salam, M.A. and Abu Affan, M. and Shamsuddin, M. and Ng, S.W. (2010) Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-kappa N)ethylidene]thiosemicarbazidato-kappa N-2(1),S}methyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (5). M570-U939. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Salam, M.A.
Abu Affan, M.
Shamsuddin, M.
Ng, S.W.
Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-kappa N)ethylidene]thiosemicarbazidato-kappa N-2(1),S}methyltin(IV)
description The monodeprotonated Schiff base ligand in the title compound, [Sn(CH3)(C14H19N4S)Cl-2], N,N',S-chelates to the Sn atom, which is six-coordinated in an octahedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent molecule, the hydrogen bond giving rise to a helical chain extending parallel to [100].
format Article
author Salam, M.A.
Abu Affan, M.
Shamsuddin, M.
Ng, S.W.
author_facet Salam, M.A.
Abu Affan, M.
Shamsuddin, M.
Ng, S.W.
author_sort Salam, M.A.
title Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-kappa N)ethylidene]thiosemicarbazidato-kappa N-2(1),S}methyltin(IV)
title_short Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-kappa N)ethylidene]thiosemicarbazidato-kappa N-2(1),S}methyltin(IV)
title_full Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-kappa N)ethylidene]thiosemicarbazidato-kappa N-2(1),S}methyltin(IV)
title_fullStr Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-kappa N)ethylidene]thiosemicarbazidato-kappa N-2(1),S}methyltin(IV)
title_full_unstemmed Dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-kappa N)ethylidene]thiosemicarbazidato-kappa N-2(1),S}methyltin(IV)
title_sort dichlorido{4-cyclohexyl-1-[1-(2-pyridyl-kappa n)ethylidene]thiosemicarbazidato-kappa n-2(1),s}methyltin(iv)
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/14275/
_version_ 1643689768969568256
score 13.15806

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