Ammonium [(1S)-(endo,anti)]-(-)-3-bromocamphor-8-sulfonate
In the title molecular salt, NH(4)(+)center dot C(10)H(14)BrO(4)S(+), the norbornane skeleton of the anion is composed of two five-membered rings in envelope conformations and a six-membered ring with one Br atom, one carbonyl O atom and a methyl group held in a boat conformation by a bridging methy...
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| Main Authors: | , , , , , |
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| Format: | Article |
| Published: |
International Union of Crystallography
2010
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/12707/ |
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| Summary: | In the title molecular salt, NH(4)(+)center dot C(10)H(14)BrO(4)S(+), the norbornane skeleton of the anion is composed of two five-membered rings in envelope conformations and a six-membered ring with one Br atom, one carbonyl O atom and a methyl group held in a boat conformation by a bridging methylene group. Short intramolecular C-H center dot center dot center dot O and C-H center dot center dot center dot Br interactions occur. In the crystal, the component ions are linked by intermolecular N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds. |
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