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Methyl 1-{4-[(S)-2-(methoxycarbonyl)-pyrrolidin-1-yl]-3,6-dioxocyclohexa-1,4 -dien-1-yl}pyrrolidine-2-carboxylate

The complete molecule of the title diproline ester quinone, C(18)H(22)N(2)O(6), is generated by a crystallographic twofold axis, which passes through the centre of the benzene ring. Both -CO(2)Me groups are orientated to the same side of the benzene ring, with the carbonyl groups pointing roughly to...

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Main Authors: Garden, S.J., Skakle, J.M.S., Tiekink, E.R.T., Wardell, J.L.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/12576/
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spelling my.um.eprints.125762019-01-31T04:10:18Z http://eprints.um.edu.my/12576/ Methyl 1-{4-[(S)-2-(methoxycarbonyl)-pyrrolidin-1-yl]-3,6-dioxocyclohexa-1,4 -dien-1-yl}pyrrolidine-2-carboxylate Garden, S.J. Skakle, J.M.S. Tiekink, E.R.T. Wardell, J.L. Q Science (General) The complete molecule of the title diproline ester quinone, C(18)H(22)N(2)O(6), is generated by a crystallographic twofold axis, which passes through the centre of the benzene ring. Both -CO(2)Me groups are orientated to the same side of the benzene ring, with the carbonyl groups pointing roughly towards each other. The conformation of the proline residue is an envelope. In the crystal, a three-dimensional network is sustained by C-H center dot center dot center dot O interactions involving both the quinone and carbonyl O atoms. International Union of Crystallography 2010 Article PeerReviewed Garden, S.J. and Skakle, J.M.S. and Tiekink, E.R.T. and Wardell, J.L. (2010) Methyl 1-{4-[(S)-2-(methoxycarbonyl)-pyrrolidin-1-yl]-3,6-dioxocyclohexa-1,4 -dien-1-yl}pyrrolidine-2-carboxylate. Acta Crystallographica Section E: Structure Reports Online, 66 (8). O2071-U1673. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Garden, S.J.
Skakle, J.M.S.
Tiekink, E.R.T.
Wardell, J.L.
Methyl 1-{4-[(S)-2-(methoxycarbonyl)-pyrrolidin-1-yl]-3,6-dioxocyclohexa-1,4 -dien-1-yl}pyrrolidine-2-carboxylate
description The complete molecule of the title diproline ester quinone, C(18)H(22)N(2)O(6), is generated by a crystallographic twofold axis, which passes through the centre of the benzene ring. Both -CO(2)Me groups are orientated to the same side of the benzene ring, with the carbonyl groups pointing roughly towards each other. The conformation of the proline residue is an envelope. In the crystal, a three-dimensional network is sustained by C-H center dot center dot center dot O interactions involving both the quinone and carbonyl O atoms.
format Article
author Garden, S.J.
Skakle, J.M.S.
Tiekink, E.R.T.
Wardell, J.L.
author_facet Garden, S.J.
Skakle, J.M.S.
Tiekink, E.R.T.
Wardell, J.L.
author_sort Garden, S.J.
title Methyl 1-{4-[(S)-2-(methoxycarbonyl)-pyrrolidin-1-yl]-3,6-dioxocyclohexa-1,4 -dien-1-yl}pyrrolidine-2-carboxylate
title_short Methyl 1-{4-[(S)-2-(methoxycarbonyl)-pyrrolidin-1-yl]-3,6-dioxocyclohexa-1,4 -dien-1-yl}pyrrolidine-2-carboxylate
title_full Methyl 1-{4-[(S)-2-(methoxycarbonyl)-pyrrolidin-1-yl]-3,6-dioxocyclohexa-1,4 -dien-1-yl}pyrrolidine-2-carboxylate
title_fullStr Methyl 1-{4-[(S)-2-(methoxycarbonyl)-pyrrolidin-1-yl]-3,6-dioxocyclohexa-1,4 -dien-1-yl}pyrrolidine-2-carboxylate
title_full_unstemmed Methyl 1-{4-[(S)-2-(methoxycarbonyl)-pyrrolidin-1-yl]-3,6-dioxocyclohexa-1,4 -dien-1-yl}pyrrolidine-2-carboxylate
title_sort methyl 1-{4-[(s)-2-(methoxycarbonyl)-pyrrolidin-1-yl]-3,6-dioxocyclohexa-1,4 -dien-1-yl}pyrrolidine-2-carboxylate
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/12576/
_version_ 1643689329563795456
score 13.209306

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