N `-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)methylidene]adamantane-1-carbo hydrazide sesquihydrate ethanol hemisolvate
In the asymmetric unit of the title compound, C(19)H(27)ClN(4)O center dot 0.5C(2)H(6)O center dot 1.5H(2)O, there are two molecules of the Schiff base, which has a rigid adamantyl cage at one end of the C(= O)NH-N=CH- chain and an almost planar [torsion angles = 1.3 (1) and 7.9 (2)degrees imidazoly...
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my.um.eprints.125642019-01-31T01:17:16Z http://eprints.um.edu.my/12564/ N `-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)methylidene]adamantane-1-carbo hydrazide sesquihydrate ethanol hemisolvate Al-Tamimi, Abdul-Malek.S. Bari, A. Al-Omar, M.A. El-Emam, A.A. Ng, S.W. Q Science (General) In the asymmetric unit of the title compound, C(19)H(27)ClN(4)O center dot 0.5C(2)H(6)O center dot 1.5H(2)O, there are two molecules of the Schiff base, which has a rigid adamantyl cage at one end of the C(= O)NH-N=CH- chain and an almost planar [torsion angles = 1.3 (1) and 7.9 (2)degrees imidazolyl ring at the other end, three molecules of water and one molecule of ethanol. In both independent molecules of the Schiff base, this chain displays an extended zigzag configuration. All their amino groups function as hydrogen-bond donors to water molecules; these are linked to other acceptor atoms, generating a layer structure. O-H...O and O-H...N interactions involving the water molecules also occur. International Union of Crystallography 2010 Article PeerReviewed Al-Tamimi, Abdul-Malek.S. and Bari, A. and Al-Omar, M.A. and El-Emam, A.A. and Ng, S.W. (2010) N `-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)methylidene]adamantane-1-carbo hydrazide sesquihydrate ethanol hemisolvate. Acta Crystallographica Section E: Structure Reports Online, 66 (8). O2131-U2191. ISSN 1600-5368 |
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Q Science (General) Al-Tamimi, Abdul-Malek.S. Bari, A. Al-Omar, M.A. El-Emam, A.A. Ng, S.W. N `-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)methylidene]adamantane-1-carbo hydrazide sesquihydrate ethanol hemisolvate |
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In the asymmetric unit of the title compound, C(19)H(27)ClN(4)O center dot 0.5C(2)H(6)O center dot 1.5H(2)O, there are two molecules of the Schiff base, which has a rigid adamantyl cage at one end of the C(= O)NH-N=CH- chain and an almost planar [torsion angles = 1.3 (1) and 7.9 (2)degrees imidazolyl ring at the other end, three molecules of water and one molecule of ethanol. In both independent molecules of the Schiff base, this chain displays an extended zigzag configuration. All their amino groups function as hydrogen-bond donors to water molecules; these are linked to other acceptor atoms, generating a layer structure. O-H...O and O-H...N interactions involving the water molecules also occur. |
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Article |
author |
Al-Tamimi, Abdul-Malek.S. Bari, A. Al-Omar, M.A. El-Emam, A.A. Ng, S.W. |
author_facet |
Al-Tamimi, Abdul-Malek.S. Bari, A. Al-Omar, M.A. El-Emam, A.A. Ng, S.W. |
author_sort |
Al-Tamimi, Abdul-Malek.S. |
title |
N `-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)methylidene]adamantane-1-carbo hydrazide sesquihydrate ethanol hemisolvate |
title_short |
N `-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)methylidene]adamantane-1-carbo hydrazide sesquihydrate ethanol hemisolvate |
title_full |
N `-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)methylidene]adamantane-1-carbo hydrazide sesquihydrate ethanol hemisolvate |
title_fullStr |
N `-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)methylidene]adamantane-1-carbo hydrazide sesquihydrate ethanol hemisolvate |
title_full_unstemmed |
N `-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)methylidene]adamantane-1-carbo hydrazide sesquihydrate ethanol hemisolvate |
title_sort |
n `-[(2-n-butyl-4-chloro-1h-imidazol-5-yl)methylidene]adamantane-1-carbo hydrazide sesquihydrate ethanol hemisolvate |
publisher |
International Union of Crystallography |
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2010 |
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http://eprints.um.edu.my/12564/ |
_version_ |
1643689326644559872 |
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13.19449 |