Cover Image

Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa 4 N 1,N 4,N 8,N 11)copper(II) diheptanoate dihydrate

The CuII atom in the title salt, [Cu(C(10)H(24)N(4))(H(2)O)(2)][CH(3)(CH(2))(5)CO(2)](2)center dot 2H(2)O, is chelated by the four N atoms of the 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand and is coordinated by two water molecules in a tetragonally Jahn-Teller-distorted octahedral geometry. T...

Full description

Saved in:
Bibliographic Details
Main Authors: Tajidi, N.S.A., Abdullah, N., Arifin, Z., Tan, K.W., Ng, S.W.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/12541/
Tags: Add Tag
No Tags, Be the first to tag this record!
id my.um.eprints.12541
record_format eprints
spelling my.um.eprints.125412019-01-30T09:04:48Z http://eprints.um.edu.my/12541/ Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa 4 N 1,N 4,N 8,N 11)copper(II) diheptanoate dihydrate Tajidi, N.S.A. Abdullah, N. Arifin, Z. Tan, K.W. Ng, S.W. Q Science (General) The CuII atom in the title salt, [Cu(C(10)H(24)N(4))(H(2)O)(2)][CH(3)(CH(2))(5)CO(2)](2)center dot 2H(2)O, is chelated by the four N atoms of the 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand and is coordinated by two water molecules in a tetragonally Jahn-Teller-distorted octahedral geometry. The CuII atom lies on a center of inversion. The cations, anions and uncoordinated water molecules are linked by N-H...O and O-H...O hydrogen bonds, forming a layer structure parallel to (100). The alkyl chain of the anion is disordered over two positions in a 0.82 (1):0.18 (1) ratio. International Union of Crystallography 2010 Article PeerReviewed Tajidi, N.S.A. and Abdullah, N. and Arifin, Z. and Tan, K.W. and Ng, S.W. (2010) Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa 4 N 1,N 4,N 8,N 11)copper(II) diheptanoate dihydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (8). M887-U283. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Tajidi, N.S.A.
Abdullah, N.
Arifin, Z.
Tan, K.W.
Ng, S.W.
Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa 4 N 1,N 4,N 8,N 11)copper(II) diheptanoate dihydrate
description The CuII atom in the title salt, [Cu(C(10)H(24)N(4))(H(2)O)(2)][CH(3)(CH(2))(5)CO(2)](2)center dot 2H(2)O, is chelated by the four N atoms of the 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand and is coordinated by two water molecules in a tetragonally Jahn-Teller-distorted octahedral geometry. The CuII atom lies on a center of inversion. The cations, anions and uncoordinated water molecules are linked by N-H...O and O-H...O hydrogen bonds, forming a layer structure parallel to (100). The alkyl chain of the anion is disordered over two positions in a 0.82 (1):0.18 (1) ratio.
format Article
author Tajidi, N.S.A.
Abdullah, N.
Arifin, Z.
Tan, K.W.
Ng, S.W.
author_facet Tajidi, N.S.A.
Abdullah, N.
Arifin, Z.
Tan, K.W.
Ng, S.W.
author_sort Tajidi, N.S.A.
title Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa 4 N 1,N 4,N 8,N 11)copper(II) diheptanoate dihydrate
title_short Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa 4 N 1,N 4,N 8,N 11)copper(II) diheptanoate dihydrate
title_full Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa 4 N 1,N 4,N 8,N 11)copper(II) diheptanoate dihydrate
title_fullStr Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa 4 N 1,N 4,N 8,N 11)copper(II) diheptanoate dihydrate
title_full_unstemmed Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa 4 N 1,N 4,N 8,N 11)copper(II) diheptanoate dihydrate
title_sort diaqua(1,4,8,11-tetraazacyclotetradecane-kappa 4 n 1,n 4,n 8,n 11)copper(ii) diheptanoate dihydrate
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/12541/
_version_ 1643689320842788864
score 13.160551

Similar Items