Bis(acetylacetonato-kappa 2 O,O')[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex
The title complex, [Cu(0.31)Ni(0.69)(C(5)H(7)O(2))(2)], was isolated from the reaction of bis(N,N-dimethyaminoethanol)copper(II) with bis(acetylacetonato)nickel(II), which yielded crystals with mixed sites at the central metal position; the refined copper-nickel occupancy ratio is 0.31 (4):0.69 (4)....
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my.um.eprints.125382019-01-30T09:10:40Z http://eprints.um.edu.my/12538/ Bis(acetylacetonato-kappa 2 O,O')[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex Shahid, M. Hamid, M. Mazhar, M. Malik, M.A. Raftery, J. QD Chemistry The title complex, [Cu(0.31)Ni(0.69)(C(5)H(7)O(2))(2)], was isolated from the reaction of bis(N,N-dimethyaminoethanol)copper(II) with bis(acetylacetonato)nickel(II), which yielded crystals with mixed sites at the central metal position; the refined copper-nickel occupancy ratio is 0.31 (4):0.69 (4). Two acetylacetonate ligands, related by a centre of symmetry, are coordinated to the central metal atom in a square-planar configuration while the methyne C atoms of the acetylacetonate ligands, ca 3.02 A away, are orthogonal to this plane at the metal site. International Union of Crystallography 2010 Article PeerReviewed Shahid, M. and Hamid, M. and Mazhar, M. and Malik, M.A. and Raftery, J. (2010) Bis(acetylacetonato-kappa 2 O,O')[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex. Acta Crystallographica Section E: Structure Reports Online, 66 (8). M949-U843. ISSN 1600-5368 |
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QD Chemistry Shahid, M. Hamid, M. Mazhar, M. Malik, M.A. Raftery, J. Bis(acetylacetonato-kappa 2 O,O')[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex |
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The title complex, [Cu(0.31)Ni(0.69)(C(5)H(7)O(2))(2)], was isolated from the reaction of bis(N,N-dimethyaminoethanol)copper(II) with bis(acetylacetonato)nickel(II), which yielded crystals with mixed sites at the central metal position; the refined copper-nickel occupancy ratio is 0.31 (4):0.69 (4). Two acetylacetonate ligands, related by a centre of symmetry, are coordinated to the central metal atom in a square-planar configuration while the methyne C atoms of the acetylacetonate ligands, ca 3.02 A away, are orthogonal to this plane at the metal site. |
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Article |
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Shahid, M. Hamid, M. Mazhar, M. Malik, M.A. Raftery, J. |
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Shahid, M. Hamid, M. Mazhar, M. Malik, M.A. Raftery, J. |
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Shahid, M. |
title |
Bis(acetylacetonato-kappa 2 O,O')[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex |
title_short |
Bis(acetylacetonato-kappa 2 O,O')[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex |
title_full |
Bis(acetylacetonato-kappa 2 O,O')[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex |
title_fullStr |
Bis(acetylacetonato-kappa 2 O,O')[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex |
title_full_unstemmed |
Bis(acetylacetonato-kappa 2 O,O')[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex |
title_sort |
bis(acetylacetonato-kappa 2 o,o')[copper(ii)nickel(ii)(0.31/0.69)]: a mixed-metal complex |
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International Union of Crystallography |
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2010 |
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http://eprints.um.edu.my/12538/ |
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1643689319977713664 |
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13.18916 |