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Bis(acetylacetonato-kappa 2 O,O')[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex

The title complex, [Cu(0.31)Ni(0.69)(C(5)H(7)O(2))(2)], was isolated from the reaction of bis(N,N-dimethyaminoethanol)copper(II) with bis(acetylacetonato)nickel(II), which yielded crystals with mixed sites at the central metal position; the refined copper-nickel occupancy ratio is 0.31 (4):0.69 (4)....

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Main Authors: Shahid, M., Hamid, M., Mazhar, M., Malik, M.A., Raftery, J.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/12538/
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spelling my.um.eprints.125382019-01-30T09:10:40Z http://eprints.um.edu.my/12538/ Bis(acetylacetonato-kappa 2 O,O')[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex Shahid, M. Hamid, M. Mazhar, M. Malik, M.A. Raftery, J. QD Chemistry The title complex, [Cu(0.31)Ni(0.69)(C(5)H(7)O(2))(2)], was isolated from the reaction of bis(N,N-dimethyaminoethanol)copper(II) with bis(acetylacetonato)nickel(II), which yielded crystals with mixed sites at the central metal position; the refined copper-nickel occupancy ratio is 0.31 (4):0.69 (4). Two acetylacetonate ligands, related by a centre of symmetry, are coordinated to the central metal atom in a square-planar configuration while the methyne C atoms of the acetylacetonate ligands, ca 3.02 A away, are orthogonal to this plane at the metal site. International Union of Crystallography 2010 Article PeerReviewed Shahid, M. and Hamid, M. and Mazhar, M. and Malik, M.A. and Raftery, J. (2010) Bis(acetylacetonato-kappa 2 O,O')[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex. Acta Crystallographica Section E: Structure Reports Online, 66 (8). M949-U843. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QD Chemistry
spellingShingle QD Chemistry
Shahid, M.
Hamid, M.
Mazhar, M.
Malik, M.A.
Raftery, J.
Bis(acetylacetonato-kappa 2 O,O')[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex
description The title complex, [Cu(0.31)Ni(0.69)(C(5)H(7)O(2))(2)], was isolated from the reaction of bis(N,N-dimethyaminoethanol)copper(II) with bis(acetylacetonato)nickel(II), which yielded crystals with mixed sites at the central metal position; the refined copper-nickel occupancy ratio is 0.31 (4):0.69 (4). Two acetylacetonate ligands, related by a centre of symmetry, are coordinated to the central metal atom in a square-planar configuration while the methyne C atoms of the acetylacetonate ligands, ca 3.02 A away, are orthogonal to this plane at the metal site.
format Article
author Shahid, M.
Hamid, M.
Mazhar, M.
Malik, M.A.
Raftery, J.
author_facet Shahid, M.
Hamid, M.
Mazhar, M.
Malik, M.A.
Raftery, J.
author_sort Shahid, M.
title Bis(acetylacetonato-kappa 2 O,O')[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex
title_short Bis(acetylacetonato-kappa 2 O,O')[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex
title_full Bis(acetylacetonato-kappa 2 O,O')[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex
title_fullStr Bis(acetylacetonato-kappa 2 O,O')[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex
title_full_unstemmed Bis(acetylacetonato-kappa 2 O,O')[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex
title_sort bis(acetylacetonato-kappa 2 o,o')[copper(ii)nickel(ii)(0.31/0.69)]: a mixed-metal complex
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/12538/
_version_ 1643689319977713664
score 13.18916

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