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Bis(mu-quinoline-2-carboxylato)-kappa 3 N,O:O;kappa 3 O:N,O-bis[(acetato-kappa 2 O,O')(methanol-kappa O)lead(II)]

The dinuclear title compound, [Pb(2)(C(10)H(6)NO(2))(2)(CH(3)COO)(2)(CH(3)OH)(2)], lies across an inversion center. The methanol-coordinated PbII atom is chelated by the acetate anion as well as by the quinoline-2-carboxylate anion. One O atom of the quinoline-2-carboxylate anion bridges two symmetr...

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Main Authors: Mohammadnezhad, G., Ghanbarpour, A.R., Amini, M.M., Ng, S.W.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/12535/
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spelling my.um.eprints.125352019-01-31T04:45:24Z http://eprints.um.edu.my/12535/ Bis(mu-quinoline-2-carboxylato)-kappa 3 N,O:O;kappa 3 O:N,O-bis[(acetato-kappa 2 O,O')(methanol-kappa O)lead(II)] Mohammadnezhad, G. Ghanbarpour, A.R. Amini, M.M. Ng, S.W. Q Science (General) The dinuclear title compound, [Pb(2)(C(10)H(6)NO(2))(2)(CH(3)COO)(2)(CH(3)OH)(2)], lies across an inversion center. The methanol-coordinated PbII atom is chelated by the acetate anion as well as by the quinoline-2-carboxylate anion. One O atom of the quinoline-2-carboxylate anion bridges two symmetry-related PbII atoms, forming the dinuclear compound. Aside from the six atoms connected to the PbII atom by regular coordination bonds, the structure features a long Pb...O interaction [3.145 (3) A] that gives rise to a distorted Psi-square-antiprismatic geometry at the metal center. The H atom of the methanol is hydrogen bonded to an O atom of the acetate. International Union of Crystallography 2010 Article PeerReviewed Mohammadnezhad, G. and Ghanbarpour, A.R. and Amini, M.M. and Ng, S.W. (2010) Bis(mu-quinoline-2-carboxylato)-kappa 3 N,O:O;kappa 3 O:N,O-bis[(acetato-kappa 2 O,O')(methanol-kappa O)lead(II)]. Acta Crystallographica Section E: Structure Reports Online, 66 (8). M963-U938. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Mohammadnezhad, G.
Ghanbarpour, A.R.
Amini, M.M.
Ng, S.W.
Bis(mu-quinoline-2-carboxylato)-kappa 3 N,O:O;kappa 3 O:N,O-bis[(acetato-kappa 2 O,O')(methanol-kappa O)lead(II)]
description The dinuclear title compound, [Pb(2)(C(10)H(6)NO(2))(2)(CH(3)COO)(2)(CH(3)OH)(2)], lies across an inversion center. The methanol-coordinated PbII atom is chelated by the acetate anion as well as by the quinoline-2-carboxylate anion. One O atom of the quinoline-2-carboxylate anion bridges two symmetry-related PbII atoms, forming the dinuclear compound. Aside from the six atoms connected to the PbII atom by regular coordination bonds, the structure features a long Pb...O interaction [3.145 (3) A] that gives rise to a distorted Psi-square-antiprismatic geometry at the metal center. The H atom of the methanol is hydrogen bonded to an O atom of the acetate.
format Article
author Mohammadnezhad, G.
Ghanbarpour, A.R.
Amini, M.M.
Ng, S.W.
author_facet Mohammadnezhad, G.
Ghanbarpour, A.R.
Amini, M.M.
Ng, S.W.
author_sort Mohammadnezhad, G.
title Bis(mu-quinoline-2-carboxylato)-kappa 3 N,O:O;kappa 3 O:N,O-bis[(acetato-kappa 2 O,O')(methanol-kappa O)lead(II)]
title_short Bis(mu-quinoline-2-carboxylato)-kappa 3 N,O:O;kappa 3 O:N,O-bis[(acetato-kappa 2 O,O')(methanol-kappa O)lead(II)]
title_full Bis(mu-quinoline-2-carboxylato)-kappa 3 N,O:O;kappa 3 O:N,O-bis[(acetato-kappa 2 O,O')(methanol-kappa O)lead(II)]
title_fullStr Bis(mu-quinoline-2-carboxylato)-kappa 3 N,O:O;kappa 3 O:N,O-bis[(acetato-kappa 2 O,O')(methanol-kappa O)lead(II)]
title_full_unstemmed Bis(mu-quinoline-2-carboxylato)-kappa 3 N,O:O;kappa 3 O:N,O-bis[(acetato-kappa 2 O,O')(methanol-kappa O)lead(II)]
title_sort bis(mu-quinoline-2-carboxylato)-kappa 3 n,o:o;kappa 3 o:n,o-bis[(acetato-kappa 2 o,o')(methanol-kappa o)lead(ii)]
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/12535/
_version_ 1643689319113687040
score 13.160551

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