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Tetrakis(4-cyanopyridine)palladium(II) bis(trifluoromethanesulfonate)

The title salt, [Pd(C(6)H(4)N(2))(4)](CF(3)SO(3))(2), comprises Pd(4-cyanopyridine)(4) dications balanced by two trifluoromethanesulfonate anions. The PdII atom lies in a square-planar geometry defined by four N atoms which form equivalent Pd-N interactions. The 4-cyanopyridine ligands are twisted o...

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Main Authors: Adrian, R.A., Gonzalez, D.M., Tiekink, E.R.T., Walmsley, J.A.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/12529/
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spelling my.um.eprints.125292019-01-31T01:39:29Z http://eprints.um.edu.my/12529/ Tetrakis(4-cyanopyridine)palladium(II) bis(trifluoromethanesulfonate) Adrian, R.A. Gonzalez, D.M. Tiekink, E.R.T. Walmsley, J.A. Q Science (General) The title salt, [Pd(C(6)H(4)N(2))(4)](CF(3)SO(3))(2), comprises Pd(4-cyanopyridine)(4) dications balanced by two trifluoromethanesulfonate anions. The PdII atom lies in a square-planar geometry defined by four N atoms which form equivalent Pd-N interactions. The 4-cyanopyridine ligands are twisted out of the N(4) plane, forming dihedral angles ranging from 66.5 (2) to 89.9 (2)degrees. In the crystal packing, columns of edge-to-edge dications define channels in which reside the anions. A range of C-H...N and C-H...O hydrogen-bonding interactions stabilizes the crystal packing. International Union of Crystallography 2010 Article PeerReviewed Adrian, R.A. and Gonzalez, D.M. and Tiekink, E.R.T. and Walmsley, J.A. (2010) Tetrakis(4-cyanopyridine)palladium(II) bis(trifluoromethanesulfonate). Acta Crystallographica Section E: Structure Reports Online, 66 (8). M957-U903. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Adrian, R.A.
Gonzalez, D.M.
Tiekink, E.R.T.
Walmsley, J.A.
Tetrakis(4-cyanopyridine)palladium(II) bis(trifluoromethanesulfonate)
description The title salt, [Pd(C(6)H(4)N(2))(4)](CF(3)SO(3))(2), comprises Pd(4-cyanopyridine)(4) dications balanced by two trifluoromethanesulfonate anions. The PdII atom lies in a square-planar geometry defined by four N atoms which form equivalent Pd-N interactions. The 4-cyanopyridine ligands are twisted out of the N(4) plane, forming dihedral angles ranging from 66.5 (2) to 89.9 (2)degrees. In the crystal packing, columns of edge-to-edge dications define channels in which reside the anions. A range of C-H...N and C-H...O hydrogen-bonding interactions stabilizes the crystal packing.
format Article
author Adrian, R.A.
Gonzalez, D.M.
Tiekink, E.R.T.
Walmsley, J.A.
author_facet Adrian, R.A.
Gonzalez, D.M.
Tiekink, E.R.T.
Walmsley, J.A.
author_sort Adrian, R.A.
title Tetrakis(4-cyanopyridine)palladium(II) bis(trifluoromethanesulfonate)
title_short Tetrakis(4-cyanopyridine)palladium(II) bis(trifluoromethanesulfonate)
title_full Tetrakis(4-cyanopyridine)palladium(II) bis(trifluoromethanesulfonate)
title_fullStr Tetrakis(4-cyanopyridine)palladium(II) bis(trifluoromethanesulfonate)
title_full_unstemmed Tetrakis(4-cyanopyridine)palladium(II) bis(trifluoromethanesulfonate)
title_sort tetrakis(4-cyanopyridine)palladium(ii) bis(trifluoromethanesulfonate)
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/12529/
_version_ 1643689317382488064
score 13.214268

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