Tetra-mu-acetato-kappa O-8:O `-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-kappa N-1]-copper(II)}
In the crystal structure of the title complex, [Cu-2(CH3COO)(4)(-)( C12H11ClN2)(2)], the complete binuclear molecule is generated by a crystallographic centre of inversion; the four acetate groups each bridge a pair of Cu-II atoms. The coordination of the metal atom is distorted octahedral within a...
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my.um.eprints.124102019-01-31T04:04:00Z http://eprints.um.edu.my/12410/ Tetra-mu-acetato-kappa O-8:O `-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-kappa N-1]-copper(II)} Fairuz, Z.A. Aiyub, Z. Abdullah, Z. Ng, S.W. Tiekink, E.R.T. Q Science (General) In the crystal structure of the title complex, [Cu-2(CH3COO)(4)(-)( C12H11ClN2)(2)], the complete binuclear molecule is generated by a crystallographic centre of inversion; the four acetate groups each bridge a pair of Cu-II atoms. The coordination of the metal atom is distorted octahedral within a donor set defined by four O atoms, the heterocyclic N atom and the second Cu atom. The pyridine ring is twisted with respect to the benzene ring, forming a dihedral angle of 33.9 (2)degrees. An intramolecular N-H center dot center dot center dot O hydrogen bond is present between the amino group and a carboxyl O atom. Intermolecular interactions of the C-H center dot center dot center dot pi type link molecules in the crystal structure. International Union of Crystallography 2010 Article PeerReviewed Fairuz, Z.A. and Aiyub, Z. and Abdullah, Z. and Ng, S.W. and Tiekink, E.R.T. (2010) Tetra-mu-acetato-kappa O-8:O `-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-kappa N-1]-copper(II)}. Acta Crystallographica Section E: Structure Reports Online, 66 (9). M1049-U173. ISSN 1600-5368 |
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Q Science (General) Fairuz, Z.A. Aiyub, Z. Abdullah, Z. Ng, S.W. Tiekink, E.R.T. Tetra-mu-acetato-kappa O-8:O `-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-kappa N-1]-copper(II)} |
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In the crystal structure of the title complex, [Cu-2(CH3COO)(4)(-)( C12H11ClN2)(2)], the complete binuclear molecule is generated by a crystallographic centre of inversion; the four acetate groups each bridge a pair of Cu-II atoms. The coordination of the metal atom is distorted octahedral within a donor set defined by four O atoms, the heterocyclic N atom and the second Cu atom. The pyridine ring is twisted with respect to the benzene ring, forming a dihedral angle of 33.9 (2)degrees. An intramolecular N-H center dot center dot center dot O hydrogen bond is present between the amino group and a carboxyl O atom. Intermolecular interactions of the C-H center dot center dot center dot pi type link molecules in the crystal structure. |
format |
Article |
author |
Fairuz, Z.A. Aiyub, Z. Abdullah, Z. Ng, S.W. Tiekink, E.R.T. |
author_facet |
Fairuz, Z.A. Aiyub, Z. Abdullah, Z. Ng, S.W. Tiekink, E.R.T. |
author_sort |
Fairuz, Z.A. |
title |
Tetra-mu-acetato-kappa O-8:O `-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-kappa N-1]-copper(II)} |
title_short |
Tetra-mu-acetato-kappa O-8:O `-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-kappa N-1]-copper(II)} |
title_full |
Tetra-mu-acetato-kappa O-8:O `-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-kappa N-1]-copper(II)} |
title_fullStr |
Tetra-mu-acetato-kappa O-8:O `-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-kappa N-1]-copper(II)} |
title_full_unstemmed |
Tetra-mu-acetato-kappa O-8:O `-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-kappa N-1]-copper(II)} |
title_sort |
tetra-mu-acetato-kappa o-8:o `-bis{[n-(4-chlorophenyl)-4-methylpyridin-2-amine-kappa n-1]-copper(ii)} |
publisher |
International Union of Crystallography |
publishDate |
2010 |
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http://eprints.um.edu.my/12410/ |
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1643689290572496896 |
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13.19449 |