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Tetra-mu-acetato-kappa O-8:O `-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-kappa N-1]-copper(II)}

In the crystal structure of the title complex, [Cu-2(CH3COO)(4)(-)( C12H11ClN2)(2)], the complete binuclear molecule is generated by a crystallographic centre of inversion; the four acetate groups each bridge a pair of Cu-II atoms. The coordination of the metal atom is distorted octahedral within a...

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Main Authors: Fairuz, Z.A., Aiyub, Z., Abdullah, Z., Ng, S.W., Tiekink, E.R.T.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/12410/
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spelling my.um.eprints.124102019-01-31T04:04:00Z http://eprints.um.edu.my/12410/ Tetra-mu-acetato-kappa O-8:O `-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-kappa N-1]-copper(II)} Fairuz, Z.A. Aiyub, Z. Abdullah, Z. Ng, S.W. Tiekink, E.R.T. Q Science (General) In the crystal structure of the title complex, [Cu-2(CH3COO)(4)(-)( C12H11ClN2)(2)], the complete binuclear molecule is generated by a crystallographic centre of inversion; the four acetate groups each bridge a pair of Cu-II atoms. The coordination of the metal atom is distorted octahedral within a donor set defined by four O atoms, the heterocyclic N atom and the second Cu atom. The pyridine ring is twisted with respect to the benzene ring, forming a dihedral angle of 33.9 (2)degrees. An intramolecular N-H center dot center dot center dot O hydrogen bond is present between the amino group and a carboxyl O atom. Intermolecular interactions of the C-H center dot center dot center dot pi type link molecules in the crystal structure. International Union of Crystallography 2010 Article PeerReviewed Fairuz, Z.A. and Aiyub, Z. and Abdullah, Z. and Ng, S.W. and Tiekink, E.R.T. (2010) Tetra-mu-acetato-kappa O-8:O `-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-kappa N-1]-copper(II)}. Acta Crystallographica Section E: Structure Reports Online, 66 (9). M1049-U173. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Fairuz, Z.A.
Aiyub, Z.
Abdullah, Z.
Ng, S.W.
Tiekink, E.R.T.
Tetra-mu-acetato-kappa O-8:O `-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-kappa N-1]-copper(II)}
description In the crystal structure of the title complex, [Cu-2(CH3COO)(4)(-)( C12H11ClN2)(2)], the complete binuclear molecule is generated by a crystallographic centre of inversion; the four acetate groups each bridge a pair of Cu-II atoms. The coordination of the metal atom is distorted octahedral within a donor set defined by four O atoms, the heterocyclic N atom and the second Cu atom. The pyridine ring is twisted with respect to the benzene ring, forming a dihedral angle of 33.9 (2)degrees. An intramolecular N-H center dot center dot center dot O hydrogen bond is present between the amino group and a carboxyl O atom. Intermolecular interactions of the C-H center dot center dot center dot pi type link molecules in the crystal structure.
format Article
author Fairuz, Z.A.
Aiyub, Z.
Abdullah, Z.
Ng, S.W.
Tiekink, E.R.T.
author_facet Fairuz, Z.A.
Aiyub, Z.
Abdullah, Z.
Ng, S.W.
Tiekink, E.R.T.
author_sort Fairuz, Z.A.
title Tetra-mu-acetato-kappa O-8:O `-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-kappa N-1]-copper(II)}
title_short Tetra-mu-acetato-kappa O-8:O `-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-kappa N-1]-copper(II)}
title_full Tetra-mu-acetato-kappa O-8:O `-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-kappa N-1]-copper(II)}
title_fullStr Tetra-mu-acetato-kappa O-8:O `-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-kappa N-1]-copper(II)}
title_full_unstemmed Tetra-mu-acetato-kappa O-8:O `-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-kappa N-1]-copper(II)}
title_sort tetra-mu-acetato-kappa o-8:o `-bis{[n-(4-chlorophenyl)-4-methylpyridin-2-amine-kappa n-1]-copper(ii)}
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/12410/
_version_ 1643689290572496896
score 13.19449

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