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(N-sec-Butyl-N-n-propyldithiocarbamato-kappa S-2,S `)triphenyltin(IV)

The Sn atom in the title compound, [Sn(C6H5)(3)(C8H16NS2)], is pentacoordinated by two S atoms, derived from an asymmetrically coordinating dithiocarbamate ligand, and three ipso-C atoms. The coordination geometry is intermediate between square-pyramidal and trigonal-bipyramidal, with a leaning towa...

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Main Authors: Awang, N., Baba, I., Yamin, B.M., Ng, S.W., Tiekink, E.R.T.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/12409/
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spelling my.um.eprints.124092019-01-31T01:13:57Z http://eprints.um.edu.my/12409/ (N-sec-Butyl-N-n-propyldithiocarbamato-kappa S-2,S `)triphenyltin(IV) Awang, N. Baba, I. Yamin, B.M. Ng, S.W. Tiekink, E.R.T. Q Science (General) The Sn atom in the title compound, [Sn(C6H5)(3)(C8H16NS2)], is pentacoordinated by two S atoms, derived from an asymmetrically coordinating dithiocarbamate ligand, and three ipso-C atoms. The coordination geometry is intermediate between square-pyramidal and trigonal-bipyramidal, with a leaning towards the latter. The presence of close intramolecular C-H center dot center dot center dot S contacts preclude the S atoms from forming significant intermolecular interactions. Rather, molecules are consolidated in the crystal structure by C-H center dot center dot center dot pi interactions. International Union of Crystallography 2010 Article PeerReviewed Awang, N. and Baba, I. and Yamin, B.M. and Ng, S.W. and Tiekink, E.R.T. (2010) (N-sec-Butyl-N-n-propyldithiocarbamato-kappa S-2,S `)triphenyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (9). M1144-U948. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Awang, N.
Baba, I.
Yamin, B.M.
Ng, S.W.
Tiekink, E.R.T.
(N-sec-Butyl-N-n-propyldithiocarbamato-kappa S-2,S `)triphenyltin(IV)
description The Sn atom in the title compound, [Sn(C6H5)(3)(C8H16NS2)], is pentacoordinated by two S atoms, derived from an asymmetrically coordinating dithiocarbamate ligand, and three ipso-C atoms. The coordination geometry is intermediate between square-pyramidal and trigonal-bipyramidal, with a leaning towards the latter. The presence of close intramolecular C-H center dot center dot center dot S contacts preclude the S atoms from forming significant intermolecular interactions. Rather, molecules are consolidated in the crystal structure by C-H center dot center dot center dot pi interactions.
format Article
author Awang, N.
Baba, I.
Yamin, B.M.
Ng, S.W.
Tiekink, E.R.T.
author_facet Awang, N.
Baba, I.
Yamin, B.M.
Ng, S.W.
Tiekink, E.R.T.
author_sort Awang, N.
title (N-sec-Butyl-N-n-propyldithiocarbamato-kappa S-2,S `)triphenyltin(IV)
title_short (N-sec-Butyl-N-n-propyldithiocarbamato-kappa S-2,S `)triphenyltin(IV)
title_full (N-sec-Butyl-N-n-propyldithiocarbamato-kappa S-2,S `)triphenyltin(IV)
title_fullStr (N-sec-Butyl-N-n-propyldithiocarbamato-kappa S-2,S `)triphenyltin(IV)
title_full_unstemmed (N-sec-Butyl-N-n-propyldithiocarbamato-kappa S-2,S `)triphenyltin(IV)
title_sort (n-sec-butyl-n-n-propyldithiocarbamato-kappa s-2,s `)triphenyltin(iv)
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/12409/
_version_ 1643689290278895616
score 13.160551

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