Cover Image

Poly[[tris(N,N-dimethylformamide)-(mu(4)-5-nitroisophthalato)(mu(3)- 5-nitroisophthalato)dicobalt(II)] N,N-dimethylformamide monosolvate]

In the polymeric title compound, [Co-2(C3H7NO)(3)(C8H3NO6)(2)]center dot C3H7NO, one 5-nitroisophthalate dianion has its two carboxylate groups chelating to one Co-II atom while simultaneously coordinating to another metal atom in a mu(4)-bridging mode. The other 5-nitroisophthalte dianion has one c...

Full description

Saved in:
Bibliographic Details
Main Authors: Su, M., Huang, Zhan-Dong, Sun, H., Yang, G., Ng, S.W.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/12204/
Tags: Add Tag
No Tags, Be the first to tag this record!
id my.um.eprints.12204
record_format eprints
spelling my.um.eprints.122042019-01-30T09:16:29Z http://eprints.um.edu.my/12204/ Poly[[tris(N,N-dimethylformamide)-(mu(4)-5-nitroisophthalato)(mu(3)- 5-nitroisophthalato)dicobalt(II)] N,N-dimethylformamide monosolvate] Su, M. Huang, Zhan-Dong Sun, H. Yang, G. Ng, S.W. Q Science (General) In the polymeric title compound, [Co-2(C3H7NO)(3)(C8H3NO6)(2)]center dot C3H7NO, one 5-nitroisophthalate dianion has its two carboxylate groups chelating to one Co-II atom while simultaneously coordinating to another metal atom in a mu(4)-bridging mode. The other 5-nitroisophthalte dianion has one carboxylate group chelating to a metal atom whereas the other bridges two metal atoms in a mu(3)-bridging mode. Both metal atoms show an octahedral coordination. The polymer adopts a layer motif, with the lattice dimethylformamide molecules occupying the space between adjacent layers. International Union of Crystallography 2010 Article PeerReviewed Su, M. and Huang, Zhan-Dong and Sun, H. and Yang, G. and Ng, S.W. (2010) Poly[[tris(N,N-dimethylformamide)-(mu(4)-5-nitroisophthalato)(mu(3)- 5-nitroisophthalato)dicobalt(II)] N,N-dimethylformamide monosolvate]. Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1220-U493. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Su, M.
Huang, Zhan-Dong
Sun, H.
Yang, G.
Ng, S.W.
Poly[[tris(N,N-dimethylformamide)-(mu(4)-5-nitroisophthalato)(mu(3)- 5-nitroisophthalato)dicobalt(II)] N,N-dimethylformamide monosolvate]
description In the polymeric title compound, [Co-2(C3H7NO)(3)(C8H3NO6)(2)]center dot C3H7NO, one 5-nitroisophthalate dianion has its two carboxylate groups chelating to one Co-II atom while simultaneously coordinating to another metal atom in a mu(4)-bridging mode. The other 5-nitroisophthalte dianion has one carboxylate group chelating to a metal atom whereas the other bridges two metal atoms in a mu(3)-bridging mode. Both metal atoms show an octahedral coordination. The polymer adopts a layer motif, with the lattice dimethylformamide molecules occupying the space between adjacent layers.
format Article
author Su, M.
Huang, Zhan-Dong
Sun, H.
Yang, G.
Ng, S.W.
author_facet Su, M.
Huang, Zhan-Dong
Sun, H.
Yang, G.
Ng, S.W.
author_sort Su, M.
title Poly[[tris(N,N-dimethylformamide)-(mu(4)-5-nitroisophthalato)(mu(3)- 5-nitroisophthalato)dicobalt(II)] N,N-dimethylformamide monosolvate]
title_short Poly[[tris(N,N-dimethylformamide)-(mu(4)-5-nitroisophthalato)(mu(3)- 5-nitroisophthalato)dicobalt(II)] N,N-dimethylformamide monosolvate]
title_full Poly[[tris(N,N-dimethylformamide)-(mu(4)-5-nitroisophthalato)(mu(3)- 5-nitroisophthalato)dicobalt(II)] N,N-dimethylformamide monosolvate]
title_fullStr Poly[[tris(N,N-dimethylformamide)-(mu(4)-5-nitroisophthalato)(mu(3)- 5-nitroisophthalato)dicobalt(II)] N,N-dimethylformamide monosolvate]
title_full_unstemmed Poly[[tris(N,N-dimethylformamide)-(mu(4)-5-nitroisophthalato)(mu(3)- 5-nitroisophthalato)dicobalt(II)] N,N-dimethylformamide monosolvate]
title_sort poly[[tris(n,n-dimethylformamide)-(mu(4)-5-nitroisophthalato)(mu(3)- 5-nitroisophthalato)dicobalt(ii)] n,n-dimethylformamide monosolvate]
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/12204/
_version_ 1643689245524623360
score 13.19449

Similar Items